Section
1 Hazards listed in Table A (HKC) / Annex I (EU SRR)
1.1 Asbestos
1.1.1 In many countries the use of asbestos was not regulated for many years, so there was no
requirement to state whether or not it was used. It was also cheap. Furthermore, asbestos
not only tends to increase the fire-fighting capabilities of compound materials, but in many
cases it assists bonding of compounds and improves strength characteristics. Therefore, it
can be expected in any place where its attributes are important, and where its addition may
not have been controlled.
1.1.4 The following Maritime Safety Committee Circulars also apply (at the time of writing):
1.1.5 Although SOLAS now prohibits the new installation of materials containing asbestos, for all
ships without exception, many countries have different asbestos legislation which means it
is impossible to make generalisations.
1.1.6 Prior to January 2011, SOLAS did not prohibit all types of asbestos. Furthermore, there has
never been one rigorously enforced law, governing all countries in the world, banning all
types of asbestos. Therefore, unless there is reputable, traceable information that proves
an item under consideration is free from asbestos, it should be treated as if it is
asbestos. This is a safe basis from which to start.
1.1.7 Table 4.1.1 ‘Indicative list’ of components which
may contain asbestos, shows an ‘indicative list’ of components which may contain
asbestos, taken from Appendix 5 - Example of the Development Process for Part I of the Inventory for Existing Ships of the Resolution MEPC.269(68) – 2015 Guidelines for the Development of the Inventory of Hazardous Materials.
Table 4.1.1 ‘Indicative list’ of components which
may contain asbestos
| Structure and/or equipment
|
Component
|
|
|
Packing with low pressure hydraulic piping
flange
|
|
|
Packing with casing
|
| Propeller shafting
|
Clutch
|
|
|
Brake lining
|
|
|
Synthetic stern tubes
|
|
|
Packing with pipe flange
|
| Diesel engine
|
Lagging material for fuel pipe
|
|
|
Lagging material for exhaust pipe
|
|
|
Lagging material turbocharger
|
|
|
Lagging material for casing
|
| Turbine engine
|
Packing with flange of piping and valve for steam line,
exhaust line and drain line
|
|
|
Lagging material for piping and valve of steam line,
exhaust line and drain line
|
|
|
|
|
|
Insulation in combustion chamber
|
|
|
Packing for casing door
|
|
|
Lagging material for exhaust pipe
|
|
|
Gasket for manhole
|
| Boiler
|
Gasket for hand hole
|
|
|
Gas shield packing for soot blower and other
hole
|
|
|
Packing with flange of piping and valve for steam line,
exhaust line, fuel line and drain line
|
|
|
Lagging material for piping and valve of steam line,
exhaust line, fuel line and drain line
|
|
|
Packing for casing door
|
|
|
Packing with manhole
|
|
|
Packing with hand hole
|
| Exhaust gas economizer
|
Gas shield packing for soot blower
|
|
|
Packing with flange of piping and valve for steam line,
exhaust line, fuel line and drain line
|
|
|
Lagging material for piping and valve of steam line,
exhaust line, fuel line and drain line
|
|
|
Packing for casing door
|
| Incinerator
|
Packing with manhole
|
|
|
Packing with hand hole
|
|
|
Lagging material for exhaust pipe
|
|
|
Packing for casing door and valve
|
| Auxiliary machinery (pump, compressor, oil purifier,
crane)
|
Gland packing
|
|
|
Brake lining
|
|
|
Packing with casing
|
| Heat exchanger
|
Gland packing for valve
|
|
|
Lagging material and insulation
|
| Valve
|
Gland packing with valve, sheet packing with piping
flange
|
|
|
Gasket with flange of high pressure and/or high
temperature
|
| Pipe, duct
|
Lagging material and insulation
|
| Tank (fuel tank, hot water tank, condenser), other equipment (fuel
strainer, lubricant oil strainer)
|
Lagging material and insulation
|
| Electric equipment
|
Insulation material
|
| Airborne asbestos
|
Wall, ceiling
|
| Ceiling, floor and wall in accommodation area
|
Ceiling, floor, wall
|
| Fire door
|
Packing, construction and insulation of the fire
door
|
| Inert gas system
|
Packing for casing etc.
|
| Air-conditioning system
|
Sheet packing, lagging material for piping and flexible
joint
|
|
|
Ropes
|
|
|
Thermal insulating materials
|
|
|
Fire shields/fire proofing
|
|
|
Space/duct insulation
|
|
|
Electrical cable materials
|
|
|
Brake linings
|
|
|
Floor tiles/deck underlay
|
|
|
Steam/water/vent flange gaskets
|
|
|
Adhesives/mastics/fillers
|
| Miscellaneous
|
Sound damping
|
|
|
Moulded plastic products
|
|
|
Sealing putty
|
|
|
Shaft/valve packing
|
|
|
Electrical bulkhead penetration packing
|
|
|
Circuit breaker arc chutes
|
|
|
Pipe hangar inserts
|
|
|
Weld shop protectors/burn covers
|
|
|
Fire-fighting blankets/clothing/equipment
|
|
|
Concrete ballast
|
1.1.8 If a ship has no asbestos-free certificate from build and/or no procurement policy in place
to restrict asbestos from being brought on board since delivery, undertaking sampling is
strongly recommended.
1.1.9 In the event that sampling is not possible due to ‘comprehensively justifiable reasons’,
any unknown material likely to contain asbestos should be treated as ‘presumed asbestos
containing materials’ and the IHM should reflect this. Furthermore, unless specific
information is provided to the contrary, the ship should be presumed to contain
asbestos.
1.1.10 Comprehensive justification for not undertaking sampling includes:
- the conclusion that it is impossible to conduct sampling without
compromising the ship’s safety and operational efficiency;
- or if it can be assumed that there will be little or no effect on disassembly as a
unit and later ship recycling and disposal operations.
- or in order to carry out a sampling check the shipowner needs to disassemble the
machinery (e.g. auxiliary boiler) in a repair yard. The costs of this check are
significantly higher than the later disposal costs at a ship recycling facility, thus
the classification as ‘potentially containing hazardous material’ is justifiable.
Note, such ‘comprehensive justification’ is equally applicable to sampling for any other
hazardous materials listed in the HKC or EU SRR.
1.2 Ozone Depleting Substances
1.2.2 The Montreal Protocol on Substances that Deplete the Ozone Layer was a convention
signed by many countries in 1987. It set out to greatly reduce the production of
materials such as CFCs and halons and has been amended several times since,
generally to make the phase-out of materials quicker.
1.2.3 Although almost all substances have been banned since 1996, HCFCs can
still be used until 2020 under the provision of the HKC. However the requirements of
the EU SRR differ (see
Ch 3, 1.1 IHM Part I hazards and their thresholds for details).
1.2.4 CFC gases were very common refrigerants on ships and halon was a popular fixed
fire-fighting medium. These gases were also used extensively as blowing agents to
produce plastics and plastic foams. Polyurethane, for example, was made using CFC
gas, and most cold store insulation and refridgerator lining was made using CFC
gases to produce the insulating foam.
1.2.5 An ‘indicative list’ for ODS can be found in Appendix 5 of the IMO
guidelines (Resolution MEPC.269(68) – 2015 Guidelines for the Development of the Inventory of Hazardous Materials), see
Table 4.1.2 ‘Indicative list’ of components which may contain ODS.
Table 4.1.2 ‘Indicative list’ of components which may contain ODS
| Materials
|
Component of equipment
|
| CFCs (R11, R12)
|
Refrigerant for refrigerators
|
| CFCs
|
Urethane formed material
|
| Blowing agents for insulation of LNG carriers
|
| Halons
|
Extinguishing agent
|
| Other fully halogenated CFCs
|
The possibility of usage in ships is low
|
| Carbon tetrachloride
|
The possibility of usage in ships is low
|
| 1,1,1-Trichloroethane
(methylchloroform)
|
The possibility of usage in ships is low
|
| HCFC (R22, R141b)
|
Refrigerant for refrigerating machine
|
| HBFC
|
The possibility of usage in ships is low
|
| Methyl bromide
|
The possibility of usage in ships is low
|
1.3 Polychlorinated biphenyls
1.3.1 Polychlorinated biphenyls (PCBs) are a family of chemicals that are good electrical
insulators, chemically stable, fireresistant and do not easily give off a vapour.
They were therefore seen as excellent components in any electrical system reliant on
the above properties. PCBs are toxic, persistent and bioaccumulative. They are
virtually insoluble in water, but highly soluble in fat (hence their bioaccumulative
properties). Under certain combustion conditions they may form highly toxic
dioxins.
1.3.2 PCBs are hard to quantify. They were generally globally phased out by legislation
between the mid-1970s and the mid- 1980s. However, phase-out dates varied round the
world and were also dependent on whether they were used in solid or liquid form.
1.3.3 For a ship built after 1992, it is extremely unlikely that it contains these
substances. As such PCB use is not thought to be a high risk for ships built after
around 1992. Nor is it thought to be a great risk on ships built before this time,
unless the ship belongs in one of the following categories:
- US built;
- related to military or potential military use;
- built before 1980;
- very large power plant and/or using liquid cooled power transformers
(specialised ships such as passenger ships, or those with very high
electrical load such as FPSOs, cable layers, offshore industry related and
hybrid/electric propulsion).
1.3.4 In older vessels, these hazards are likely to exist in transformers,
fluorescent lighting ballasts, paints, wire insulation and electric motor start up
capacitors. An ‘indicative list’ for PCBs can be found in Appendix 5 of the IMO
Guidelines MEPC.269(68), see
Table 4.1.3 ‘Indicative list’ of components which may contain PCBs.
Table 4.1.3 ‘Indicative list’ of components which may contain PCBs
| Equipment
|
Component of equipment
|
| Transformer
|
Insulating oil
|
| Condenser
|
Insulating oil
|
| Fuel heater
|
Heating medium
|
| Electric cable
|
Covering insulating tape
|
| Lubricating oil
|
|
| Heat oil
|
Thermometers, sensors, indicators
|
| Rubber/felt gaskets
|
|
| Rubber hose
|
|
| Plastic foam insulation
|
|
| Thermal insulating materials
|
|
| Voltage regulators
|
|
| Switches/reclosers/brushings
|
|
| Electromagnets
|
|
| Adhesives/tapes
|
|
| Surface contamination of machinery
|
|
| Oil-based paint
|
|
| Caulking
|
|
| Rubber isolation mounts
|
|
| Pipe hangers
|
|
| Light ballasts (component within fluorescent light
fixtures)
|
|
| Plasticisers
|
|
| Felt under septum on top of hull bottom
|
|
1.4 Organotin compounds
1.4.1 TBT is an organic compound containing tin. It was first used in the 1960s
as an anti-fouling agent and was highly effective. However, it is an endocrine
disrupting chemical which interferes with hormones, and adverse impacts became
evident in shellfish from the 1970s. This led to the development and adoption of the
International Convention on the Control of Harmful Anti-fouling Systems on
Ships in October 2001 (AFS - International Convention on the Control of Harmful Anti-Fouling Systems on Ships, 2001), which will ultimately lead to the phase-out of
TBT-based anti-fouling paints.
1.4.2 TBT paints are only expected to be found on the external underwater parts of the
ship, unless there is a known reason why they are applied elsewhere. Most ships now
comply with the AFS Convention. As such the AFS certificate should detail whether
the ship uses, or has sealed, TBT anti-fouling.
1.5 Perfluorooctane sulfonic acid (for EU SRR only)
1.5.1 Perfluorooctane sulfonic acid (PFOS) is chronically toxic, injurious to reproduction,
carcinogenic, toxic to aquatic organisms and widely distributed in the global
environment. In the marine industry, it can be found in fire-fighting foams on
vessels carrying inflammable fluids and those with helicopter decks, rubber and
plastic materials (i.e. cable sheaths, PVC flooring, gaskets and seals) and coatings
(i.e. paint).
1.5.2 The main application on board ships is considered to be fire-fighting foams of the
type AFFF (aqueous film forming foams). PFOS-containing AFFF could be applied on
board a range of ship types, but the larger volumes are usually installed on vessels
carrying inflammable fluids, and on vessels with helicopter decks. Volumes normally
range from some 100 litres to 10 000 litres, depending on the type and size of the
vessel. The foam is typically stored in one tank serving a main system, potentially
with additional smaller and separate devices (e.g. 20 litres), usually in the
machinery room(s).
1.5.3 An indicative list of materials/items which may contain PFOS is
summarised in Table 4.1.4 ‘Indicative list’ of components which may contain PFOS, which is adapted from EMSA’s Best Practice Guidance on the
Inventory of Hazardous Materials and EMSA Study of two hazardous substances (PFOS
and HBCDD).
Table 4.1.4 ‘Indicative list’ of components which may contain PFOS
| Item
|
Occurrence
|
Relevance to IHM (if present)
|
Other information
|
| Fire-fighting foams
(e.g.
AFFF,
FFFP,
AR-AFFF,
AR-FFFP)
|
Pre 2002 – fire-fighting foam concentrate may
contain PFOS and needs to be analysed/declared.
2002–2010 – PFOS containing fire-fighting foam
concentrate may have been brought on board vessels.
Post 2010 – PFOS containing firefighting
foams is less likely on board vessels at all, unless vessels are
built in China, where it at that time and still is legal to
produce and sell.
|
Part I
|
For fixed fire-fighting foam systems, typical volumes
range from 400 to 19 000 litres of foam concentrate, with a possible
PFOS content of 0,5–1,5%. This concentrate is mixed with typically
94% or 97% water to produce the foam.
|
| AFFF typically stored in one tank serving a main
system, potentially with smaller and separate devices.
|
| Incomplete emptying of tanks and hoses, previously holding PFOS
containing foam concentrate, may contaminate new non-PFOS containing
foam above the threshold level, hence sampling and analysis is
recommended.
|
| Protective coatings
for fabrics such as carpets, textiles, upholstery
|
Typically applied as
coatings to protect the fabrics. Fabrics and textiles are relevant
for all ship and rig types in areas such as accommodation areas,
offices and passageways.
|
Part I (if carpet is glued
to the floor) otherwise;
|
Assumed to be present at
a level 1% of the polymer.
|
| Part III
|
| Paints and coatings
|
Not expected to find PFOS in paint
and coatings because other (less expensive) surfactants are probably
used.
|
Part I
|
|
| Electronics – semiconductors and
photolithography
|
In electrical products with semiconductors
(transistors, diodes) and photographic equipment such as printing
plates, photo paper and photographic films.
|
Part III
|
Obvious areas are technical rooms such as bridge
and control rooms
|
| Sealants and
adhesive products
|
Wide area of use and can
be found on a variety of locations where sealants and adhesive
products are applied, such as tube and pipe ends, glues, around
gaskets and more.
|
Yes – but depends on
the item for specific Part of IHM
|
Listed in UNEP
(2010).
|
| Low volumes of PFOS used in sealants
and adhesive product but no detail regarding production or
quantities is given.
|
| Toner and printing inks
|
Limited use. Mainly related to printers and
copying machines used as an additive.
|
Part III
|
A PFOS content 100 mg/kg or 0,01%. Limited usage
– according to OECD (2006) less than 1 tonne used globally as
additive.
|
| Drilling fluids
|
Drilling fluids are only relevant
for drilling units/rigs.
|
Yes – but depends on the specific use
|
There are designated areas
on a rig where drilling fluids and mud is handled.
|
|