Section 1 Hazards listed in Table A (HKC) / Annex I (EU SRR)
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Clasifications Register Guidance Information - Guidance Note for the Inventory of Hazardous Materials, July 2019 - Chapter 4 Hazards to be recorded in the IHM - Section 1 Hazards listed in Table A (HKC) / Annex I (EU SRR)

Section 1 Hazards listed in Table A (HKC) / Annex I (EU SRR)

1.1 Asbestos

1.1.1 In many countries the use of asbestos was not regulated for many years, so there was no requirement to state whether or not it was used. It was also cheap. Furthermore, asbestos not only tends to increase the fire-fighting capabilities of compound materials, but in many cases it assists bonding of compounds and improves strength characteristics. Therefore, it can be expected in any place where its attributes are important, and where its addition may not have been controlled.

1.1.2 Since 1 July 2002, the installation of materials that contain asbestos was prohibited (with the exception of certain vanes, joints and insulation) under Chapter II-1 - Construction - Structure, subdivision and stability, machinery and electrical installations, for all ships.

1.1.3 Resolution MSC.282(86) – Adoption of Amendments to the International Convention for the Safety of Life at Sea, 1974, as Amended – (adopted on 5 June 2009) introduced amendments to Regulation 3-5 - New installation of materials containing asbestos, prohibiting the new installation of materials containing asbestos, for all ships without exceptions, from 1 January 2011.

1.1.5 Although SOLAS now prohibits the new installation of materials containing asbestos, for all ships without exception, many countries have different asbestos legislation which means it is impossible to make generalisations.

1.1.6 Prior to January 2011, SOLAS did not prohibit all types of asbestos. Furthermore, there has never been one rigorously enforced law, governing all countries in the world, banning all types of asbestos. Therefore, unless there is reputable, traceable information that proves an item under consideration is free from asbestos, it should be treated as if it is asbestos. This is a safe basis from which to start.

1.1.7 Table 4.1.1 ‘Indicative list’ of components which may contain asbestos, shows an ‘indicative list’ of components which may contain asbestos, taken from Appendix 5 - Example of the Development Process for Part I of the Inventory for Existing Ships of the Resolution MEPC.269(68) – 2015 Guidelines for the Development of the Inventory of Hazardous Materials.

Table 4.1.1 ‘Indicative list’ of components which may contain asbestos

Structure and/or equipment Component
  Packing with low pressure hydraulic piping flange
  Packing with casing
Propeller shafting Clutch
  Brake lining
  Synthetic stern tubes
  Packing with pipe flange
Diesel engine Lagging material for fuel pipe
  Lagging material for exhaust pipe
  Lagging material turbocharger
  Lagging material for casing
Turbine engine Packing with flange of piping and valve for steam line, exhaust line and drain line
  Lagging material for piping and valve of steam line, exhaust line and drain line
   
  Insulation in combustion chamber
  Packing for casing door
  Lagging material for exhaust pipe
  Gasket for manhole
Boiler Gasket for hand hole
  Gas shield packing for soot blower and other hole
  Packing with flange of piping and valve for steam line, exhaust line, fuel line and drain line
  Lagging material for piping and valve of steam line, exhaust line, fuel line and drain line
  Packing for casing door
  Packing with manhole
  Packing with hand hole
Exhaust gas economizer Gas shield packing for soot blower
  Packing with flange of piping and valve for steam line, exhaust line, fuel line and drain line
  Lagging material for piping and valve of steam line, exhaust line, fuel line and drain line
  Packing for casing door
Incinerator Packing with manhole
  Packing with hand hole
  Lagging material for exhaust pipe
  Packing for casing door and valve
Auxiliary machinery (pump, compressor, oil purifier, crane) Gland packing
  Brake lining
  Packing with casing
Heat exchanger Gland packing for valve
  Lagging material and insulation
Valve Gland packing with valve, sheet packing with piping flange
  Gasket with flange of high pressure and/or high temperature
Pipe, duct Lagging material and insulation
Tank (fuel tank, hot water tank, condenser), other equipment (fuel strainer, lubricant oil strainer) Lagging material and insulation
Electric equipment Insulation material
Airborne asbestos Wall, ceiling
Ceiling, floor and wall in accommodation area Ceiling, floor, wall
Fire door Packing, construction and insulation of the fire door
Inert gas system Packing for casing etc.
Air-conditioning system Sheet packing, lagging material for piping and flexible joint
  Ropes
  Thermal insulating materials
  Fire shields/fire proofing
  Space/duct insulation
  Electrical cable materials
  Brake linings
  Floor tiles/deck underlay
  Steam/water/vent flange gaskets
  Adhesives/mastics/fillers
Miscellaneous Sound damping
  Moulded plastic products
  Sealing putty
  Shaft/valve packing
  Electrical bulkhead penetration packing
  Circuit breaker arc chutes
  Pipe hangar inserts
  Weld shop protectors/burn covers
  Fire-fighting blankets/clothing/equipment
  Concrete ballast

1.1.8 If a ship has no asbestos-free certificate from build and/or no procurement policy in place to restrict asbestos from being brought on board since delivery, undertaking sampling is strongly recommended.

1.1.9 In the event that sampling is not possible due to ‘comprehensively justifiable reasons’, any unknown material likely to contain asbestos should be treated as ‘presumed asbestos containing materials’ and the IHM should reflect this. Furthermore, unless specific information is provided to the contrary, the ship should be presumed to contain asbestos.

1.1.10 Comprehensive justification for not undertaking sampling includes:
  • the conclusion that it is impossible to conduct sampling without compromising the ship’s safety and operational efficiency;
  • or if it can be assumed that there will be little or no effect on disassembly as a unit and later ship recycling and disposal operations.
  • or in order to carry out a sampling check the shipowner needs to disassemble the machinery (e.g. auxiliary boiler) in a repair yard. The costs of this check are significantly higher than the later disposal costs at a ship recycling facility, thus the classification as ‘potentially containing hazardous material’ is justifiable.

Note, such ‘comprehensive justification’ is equally applicable to sampling for any other hazardous materials listed in the HKC or EU SRR.

1.2 Ozone Depleting Substances

1.2.1 Ozone-depleting substances (ODS) are gases, such as CFCs and halons. ODS have been controlled according to the Montreal Protocol and MARPOL - International Convention for the Prevention of Pollution from Ships.

1.2.2 The Montreal Protocol on Substances that Deplete the Ozone Layer was a convention signed by many countries in 1987. It set out to greatly reduce the production of materials such as CFCs and halons and has been amended several times since, generally to make the phase-out of materials quicker.

1.2.3 Although almost all substances have been banned since 1996, HCFCs can still be used until 2020 under the provision of the HKC. However the requirements of the EU SRR differ (see Ch 3, 1.1 IHM Part I hazards and their thresholds for details).

1.2.4 CFC gases were very common refrigerants on ships and halon was a popular fixed fire-fighting medium. These gases were also used extensively as blowing agents to produce plastics and plastic foams. Polyurethane, for example, was made using CFC gas, and most cold store insulation and refridgerator lining was made using CFC gases to produce the insulating foam.

1.2.5 An ‘indicative list’ for ODS can be found in Appendix 5 of the IMO guidelines (Resolution MEPC.269(68) – 2015 Guidelines for the Development of the Inventory of Hazardous Materials), see Table 4.1.2 ‘Indicative list’ of components which may contain ODS.

Table 4.1.2 ‘Indicative list’ of components which may contain ODS

Materials Component of equipment
CFCs (R11, R12) Refrigerant for refrigerators
CFCs Urethane formed material
Blowing agents for insulation of LNG carriers
Halons Extinguishing agent
Other fully halogenated CFCs The possibility of usage in ships is low
Carbon tetrachloride The possibility of usage in ships is low
1,1,1-Trichloroethane (methylchloroform) The possibility of usage in ships is low
HCFC (R22, R141b) Refrigerant for refrigerating machine
HBFC The possibility of usage in ships is low
Methyl bromide The possibility of usage in ships is low

1.3 Polychlorinated biphenyls

1.3.1 Polychlorinated biphenyls (PCBs) are a family of chemicals that are good electrical insulators, chemically stable, fireresistant and do not easily give off a vapour. They were therefore seen as excellent components in any electrical system reliant on the above properties. PCBs are toxic, persistent and bioaccumulative. They are virtually insoluble in water, but highly soluble in fat (hence their bioaccumulative properties). Under certain combustion conditions they may form highly toxic dioxins.

1.3.2 PCBs are hard to quantify. They were generally globally phased out by legislation between the mid-1970s and the mid- 1980s. However, phase-out dates varied round the world and were also dependent on whether they were used in solid or liquid form.

1.3.3 For a ship built after 1992, it is extremely unlikely that it contains these substances. As such PCB use is not thought to be a high risk for ships built after around 1992. Nor is it thought to be a great risk on ships built before this time, unless the ship belongs in one of the following categories:
  • US built;
  • related to military or potential military use;
  • built before 1980;
  • very large power plant and/or using liquid cooled power transformers (specialised ships such as passenger ships, or those with very high electrical load such as FPSOs, cable layers, offshore industry related and hybrid/electric propulsion).

1.3.4 In older vessels, these hazards are likely to exist in transformers, fluorescent lighting ballasts, paints, wire insulation and electric motor start up capacitors. An ‘indicative list’ for PCBs can be found in Appendix 5 of the IMO Guidelines MEPC.269(68), see Table 4.1.3 ‘Indicative list’ of components which may contain PCBs.

Table 4.1.3 ‘Indicative list’ of components which may contain PCBs

Equipment Component of equipment
Transformer Insulating oil
Condenser Insulating oil
Fuel heater Heating medium
Electric cable Covering insulating tape
Lubricating oil  
Heat oil Thermometers, sensors, indicators
Rubber/felt gaskets  
Rubber hose  
Plastic foam insulation  
Thermal insulating materials  
Voltage regulators  
Switches/reclosers/brushings  
Electromagnets  
Adhesives/tapes  
Surface contamination of machinery  
Oil-based paint  
Caulking  
Rubber isolation mounts  
Pipe hangers  
Light ballasts (component within fluorescent light fixtures)  
Plasticisers  
Felt under septum on top of hull bottom  

1.4 Organotin compounds

1.4.1 TBT is an organic compound containing tin. It was first used in the 1960s as an anti-fouling agent and was highly effective. However, it is an endocrine disrupting chemical which interferes with hormones, and adverse impacts became evident in shellfish from the 1970s. This led to the development and adoption of the International Convention on the Control of Harmful Anti-fouling Systems on Ships in October 2001 (AFS - International Convention on the Control of Harmful Anti-Fouling Systems on Ships, 2001), which will ultimately lead to the phase-out of TBT-based anti-fouling paints.

1.4.2 TBT paints are only expected to be found on the external underwater parts of the ship, unless there is a known reason why they are applied elsewhere. Most ships now comply with the AFS Convention. As such the AFS certificate should detail whether the ship uses, or has sealed, TBT anti-fouling.

1.5 Perfluorooctane sulfonic acid (for EU SRR only)

1.5.1 Perfluorooctane sulfonic acid (PFOS) is chronically toxic, injurious to reproduction, carcinogenic, toxic to aquatic organisms and widely distributed in the global environment. In the marine industry, it can be found in fire-fighting foams on vessels carrying inflammable fluids and those with helicopter decks, rubber and plastic materials (i.e. cable sheaths, PVC flooring, gaskets and seals) and coatings (i.e. paint).

1.5.2 The main application on board ships is considered to be fire-fighting foams of the type AFFF (aqueous film forming foams). PFOS-containing AFFF could be applied on board a range of ship types, but the larger volumes are usually installed on vessels carrying inflammable fluids, and on vessels with helicopter decks. Volumes normally range from some 100 litres to 10 000 litres, depending on the type and size of the vessel. The foam is typically stored in one tank serving a main system, potentially with additional smaller and separate devices (e.g. 20 litres), usually in the machinery room(s).

1.5.3 An indicative list of materials/items which may contain PFOS is summarised in Table 4.1.4 ‘Indicative list’ of components which may contain PFOS, which is adapted from EMSA’s Best Practice Guidance on the Inventory of Hazardous Materials and EMSA Study of two hazardous substances (PFOS and HBCDD).

Table 4.1.4 ‘Indicative list’ of components which may contain PFOS

Item Occurrence Relevance to IHM (if present) Other information
Fire-fighting foams

(e.g.

AFFF,

FFFP,

AR-AFFF,

AR-FFFP)

Pre 2002 – fire-fighting foam concentrate may contain PFOS and needs to be analysed/declared.

2002–2010 – PFOS containing fire-fighting foam concentrate may have been brought on board vessels.

Post 2010 – PFOS containing firefighting foams is less likely on board vessels at all, unless vessels are built in China, where it at that time and still is legal to produce and sell.

Part I For fixed fire-fighting foam systems, typical volumes range from 400 to 19 000 litres of foam concentrate, with a possible PFOS content of 0,5–1,5%. This concentrate is mixed with typically 94% or 97% water to produce the foam.
AFFF typically stored in one tank serving a main system, potentially with smaller and separate devices.
Incomplete emptying of tanks and hoses, previously holding PFOS containing foam concentrate, may contaminate new non-PFOS containing foam above the threshold level, hence sampling and analysis is recommended.
Protective coatings for fabrics such as carpets, textiles, upholstery Typically applied as coatings to protect the fabrics. Fabrics and textiles are relevant for all ship and rig types in areas such as accommodation areas, offices and passageways. Part I (if carpet is glued to the floor) otherwise; Assumed to be present at a level 1% of the polymer.
Part III
Paints and coatings Not expected to find PFOS in paint and coatings because other (less expensive) surfactants are probably used. Part I  
Electronics – semiconductors and photolithography In electrical products with semiconductors (transistors, diodes) and photographic equipment such as printing plates, photo paper and photographic films. Part III Obvious areas are technical rooms such as bridge and control rooms
Sealants and adhesive products Wide area of use and can be found on a variety of locations where sealants and adhesive products are applied, such as tube and pipe ends, glues, around gaskets and more. Yes – but depends on the item for specific Part of IHM Listed in UNEP (2010).
Low volumes of PFOS used in sealants and adhesive product but no detail regarding production or quantities is given.
Toner and printing inks Limited use. Mainly related to printers and copying machines used as an additive. Part III A PFOS content 100 mg/kg or 0,01%. Limited usage – according to OECD (2006) less than 1 tonne used globally as additive.
Drilling fluids Drilling fluids are only relevant for drilling units/rigs. Yes – but depends on the specific use There are designated areas on a rig where drilling fluids and mud is handled.

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