Section
2 Hazards listed in Table A (HKC) / Annex II (EU SRR)
2.1 Overview
2.1.2 An ‘indicative list’ for Table B hazards, which can be found in Appendix 5 - Example of the Development Process for Part I of the Inventory for Existing Ships of the IMO Guidelines (Resolution MEPC.269(68) – 2015 Guidelines for the Development of the Inventory of Hazardous Materials), is summarised in Table 4.2.1 ‘Indicative list’ of Table B (HKC) hazards.
Table 4.2.1 ‘Indicative list’ of Table B (HKC) hazards
Materials
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Component of equipment
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Cadmium and cadmium compounds
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Plating film, bearing
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Hexavalent Chromium compounds
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Plating film
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Mercury and mercury compounds
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Fluorescent light, mercury lamp, mercury cell, liquid-level
switch, gyro compass, thermometer, measuring tool, manganese cell,
pressure sensors, light fittings, electrical switches, fire
detectors
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Lead and lead compounds
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Corrosion resistant primer, solder (almost all electric
appliances contain solder), paints, preservative coatings, cable
insulation, lead ballast, generators
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Polybrominated biphenyls (PBBs)
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Non-flammable plastics
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Polybrominated diphenyl ethers (PBDEs)
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Non-flammable plastics
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Polychlorinated naphthalenes
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Paint, lubricating oil
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Radioactive
substances
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Appendix 10 of
MEPC.269(68)
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Examples of consumer products with
radioactive materials
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Ionisation chamber smoke detectors
(typical radionuclides 241Am; 226Ra)
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Instruments/signs containing gaseous
tritium light sources (3H)
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Instruments/signs containing radioactive
painting (typical radionuclide 226Ra)
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High intensity discharge lamps (typical
radionuclides 85Kr; 232Th)
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Radioactive lighting rods (typical
radionuclides 241Am; 226Ra)
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Examples of industrial gauges with
radioactive materials
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Radioactive level gauges
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Radioactive dredger gauges*
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Radioactive conveyor gauges*
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Radioactive spinning pipe gauges*
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Certain short-chain chlorinated paraffins
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Non-flammable plastics
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* Typical radionuclides:
241Am; 241Am/Be; 252Cf;
244Cm; 60Co; 137Cs;
153Gd; 192Ir; 147Pm;
238Pu; 239Pu/Be; 226Ra;
75S; 90Sr (90Y);
170Tm; 169Yb
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2.2 Cadmium and cadmium-containing compounds
2.2.1 Cadmium has historically had many uses. Cadmium is used on board ships as an alloy in
bearings and other components. Another main use is as a dye for textiles and
plastics. It is used to produce yellow or orange and so it may be present in any
yellow or orange materials or plastics.
2.3 Hexavalent chromium and chromium-containing compounds
2.3.1 Hexavalent chromium is used in passivating layers, not only as an electroplated
layer, but also, in high percentages, in passivating paints.
2.4 Mercury and mercury compounds
2.4.1 Elemental mercury is common in instruments for measuring temperature and pressure,
and also in switches and fluorescent lights. Mercury can fatally damage the brain
and the kidneys. Low levels of exposure in prospective mothers can severely damage
babies and children. Inhaled mercury is very toxic and mercury will evaporate
slowly; a broken thermometer can contaminate a room to toxic levels.
2.4.2 Mercury is found in switches, ballast gauge systems, thermometers and fluorescent
lights.
2.4.3 Fluorescent lights generally contain small amounts of mercury; pre-1988 tubes may
contain about 45 mg per tube. It is therefore recommended that all tubes are
declared as containing mercury, unless other information is readily available.
2.5 Lead and lead-containing compounds
2.5.1 Lead is a very common additive; solder is a well-known use.
2.6 Polybrominated biphenyls
2.6.1 Polybrominated biphenyls (PBBs) are similar to PCBs. They are used as flame
retardants, especially in textiles and plastics.
2.7 Polybrominated diphenyl ethers
2.7.1 Polybrominated diphenyl ethers (PBDEs) are used as flame retardants.
2.8 Polychlorinated naphthalenes
2.8.1 Polychlorinated naphthalenes (PCNs) have been used in many electrical devices, but
also for the impregnation of woods and textiles to make them waterproof,
flame-resistant and protect against moulds.
2.9 Radioactive substances
2.9.1 These items are relatively well understood and several recycling ports are known to
require radiation surveys before arrival. The likelihood of genuine risk is thought
to be exceptionally low.
2.9.2 The most common use of radioactive materials is in ionising smoke detectors. These
generally use americium-241. All detector heads must be on the approved Fire
Control/Safety Plan, and this can easily be checked and included in the IHM.
2.9.3 Radioactive elements may also be used in tank sounding and ullage devices, radars and
radioluminescent (emergency) signs.
2.9.4 Other items that might need consideration include carriage of radioactive materials
and cargo, such as drilling mud or spent nuclear fuel. Naturally occurring
radioactive materials (radionuclides) may be present in drilling mud or firebricks.
Once again, the services of a recognised expert would be recommended, especially if
a heightened risk is associated with an offshore supply ship or a nuclear fuel
carrier, for example.
2.10 Certain short-chained chlorinated paraffins
2.10.1 According to the US EPA the largest use of short-chained chlorinated paraffins is as
a component of lubricants and coolants in metal cutting and metal forming
operations. The second-largest use is as both a secondary plasticiser and a flame
retardant in plastics, especially PVC. Other minor domestic uses are as a
plasticiser and a flame-retardant additive to a variety of products including:
rubber formulations, paints and other coatings, and adhesives and sealants.
2.11 Brominated flame retardant (EU SRR only)
2.11.1 Brominated flame retardant (HBCDD) is used as flame retardant additive, providing
fire protection during the service life of vehicles, buildings or articles, as well
as protection while stored. The main uses of HBCDD globally are in expanded (EPS)
and extruded (XPS) polystyrene foam insulation while the use in textile applications
and electric and electronic appliances is smaller.
2.11.2 An indicative list of materials/items which may contain HBCDD is
summarised in Table 4.2.2 ‘Indicative list’ of components which may contain HBCDD which is adapted from EMSA’s Best Practice Guidance on the
Inventory of Hazardous Materials. The information in this Table is synthesised from
both the EMSA’s Best Practice Guidance on the Inventory of Hazardous Materials
and EMSA Study of two hazardous substances (PFOS and HBCDD).
Table 4.2.2 ‘Indicative list’ of components which may contain HBCDD
Item
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Occurrence
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Relevance to IHM
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Other information
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XPS and EPS foam
- Flooring
- Cold storage
- Transportations
- Tank insulation (LPG, LEG and LNG
tank)
- other foam insulation
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Used in building and construction
industry to meet fire safety standards, for insulation, moisture
barrier, protect against damage from freezing, provide stable fill
material and create high strength composite materials.
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Yes – but
depends on the item for specific Part of IHM
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Profiles of HBCDD
in European markets (year 2006/2007) indicate that 96% of HBCDD is
related to EPS and XPS, meaning only a small fraction in HIPS and
textiles. Typically content of 0.7% by weight in XPS and 0.5–2% in
general.
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Can be found on board all vessels and rig
types and should be considered for insulation used in the walls and
ceiling of cold provision rooms. In addition to the above, it is
recommended that special attention is paid to insulation on board
reefers, insulation in refrigerated containers and insulation of
LPG, LEG and LNG tanks.
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- Flooring insulation – e.g. vinyl
floorings in accommodation areas.
- Cold storage – e.g. foam insulation of
cold provision rooms, etc.
- Transportation – e.g. shipping
containers, electrical parts
- Tank insulation – to achieve thermal
efficiency, improved insulation lifetime and low need for
maintenance.
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Textile back
coatings
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Used as flame retardant in textiles,
carpets, rugs, furniture and fabrics.
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Part
III
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Concentration 2.2–4.3%
in the textiles
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Can be found on board all vessels and rig types and
relevant items are carpets, furniture and vinyl flooring in
accommodation areas, offices and passageways especially.
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High impact polystyrene
(HIPS)
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Can be found on board all vessels and units and
relevant for resistant plastic used computer housings and instrument
panels especially. Relevant areas are bridge, offices and control
rooms.
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Part III
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