ALUMINIUM SMELTING BY-PRODUCTS or ALUMINIUM REMELTING BY-PRODUCTS UN 3170
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Statutory Documents - IMO Publications and Documents - International Codes - IMSBC Code – International Maritime Solid Bulk Cargoes Code – Resolution MSC.268(85) - Appendix 1 – Individual Schedules of Solid Bulk Cargoes - ALUMINIUM SMELTING BY-PRODUCTS or ALUMINIUM REMELTING BY-PRODUCTS UN 3170

ALUMINIUM SMELTING BY-PRODUCTS or ALUMINIUM REMELTING BY-PRODUCTS UN 3170

Description

Aluminium smelting by-products are wastes from the aluminium manufacturing process. Grey or black powder or lumps with some metallic inclusions. The term encompasses various different waste materials, which include but are not limited to:

Aluminium dross Spent cathodes
Aluminium salt slags Spent potliner
Aluminium skimmings  

Characteristics

Physical properties
Size Angle of repose Bulk density (kg/m3) Stowage factor (m3/t)
Not applicable Not applicable 1,220 0.82
Hazard classification
Class Subsidiary hazard(s) MHB Group
4.3 Not applicable   B

Hazard

Contact with water may cause heating with possible evolution of flammable and toxic gases such as hydrogen, ammonia and acetylene.

Fire is unlikely but may follow an explosion of flammable gas and will be difficult to extinguish. In port, flooding may be considered, but due consideration should be given to stability.

This cargo is non-combustible or has a low fire risk.

Stowage and segregation

"Separated from" foodstuffs and all class 8 liquids.

Hold cleanliness

Clean and dry as relevant to the hazards of the cargo.

Weather precautions

This cargo shall be kept as dry as practicable. This cargo shall not be handled during precipitation. During handling of this cargo, all non-working hatches of the cargo spaces into which this cargo is loaded, or to be loaded, shall be closed.

Loading

Trim in accordance with the relevant provisions required under sections 4 and 5 of this Code.

Precautions

Prior to loading this cargo, a certificate shall be provided by the manufacturer or shipper stating that, after manufacture, the material was stored under cover, but exposed to the weather in the particle size to be shipped, for not less than 3 days prior to shipment. Whilst the ship is alongside and the hatches of the cargo spaces containing this cargo are closed, the mechanical ventilation shall be operated continuously as weather permits. During handling of this cargo, "NO SMOKING" signs shall be posted on decks and in areas adjacent to cargo spaces and no naked lights shall be permitted in these areas. At least two self-contained breathing apparatus, in addition to those required by SOLAS regulation II-2/10.10, shall be provided on board. Bulkheads between the cargo spaces and the engine-room shall be gastight. Inadvertent pumping through machinery spaces shall be avoided.

Ventilation

Continuous mechanical ventilation shall be conducted during the voyage for the cargo spaces carrying this cargo. If maintaining ventilation endangers the ship or the cargo, it may be interrupted unless there is a risk of explosion or other danger due to interruption of the ventilation. In any case mechanical ventilation shall be maintained for a reasonable period prior to discharge. Ventilation shall be arranged such that any escaping gases are minimized from reaching living quarters on or under the deck.

Carriage

For quantitative measurements of hydrogen, ammonia and acetylene, suitable detectors for each gas or combination of gases shall be on board while this cargo is carried. The detectors shall be of certified safe type for use in explosive atmosphere. The concentrations of these gases in the cargo spaces carrying this cargo shall be measured regularly, during the voyage, and the results of the measurements shall be recorded and kept on board.

Discharge

No special requirements.

Clean-up

Water shall not be used for cleaning of the cargo space which has contained this cargo, because of danger of gas.

Emergency procedures

Special emergency equipment to be carried
Nil
Emergency procedures
Nil
Emergency action in the event of fire
Batten down and use CO2, if available. Do not use water. If this proves ineffective, endeavour to stop fire from spreading and head for the nearest suitable port.
Medical first aid
Refer to the Medical First Aid Guide (MFAG), as amended.

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