Although having many different physical characteristics,
fuel oil mainly consists of hydrocarbons, e.g. C15H32.
C has an atomic weight of 12.011, while Hydrogen (H) has 1. This yields
carbon with a mass fraction limited to the range of 85 % to 87.5 %,
where diesel oil is in the higher % range and heavy fuel oil in the
lower % range. When combusted hydrocarbons react with oxygen (O),
which have an atomic weight of 15.9994 then for each CO2 one
C is needed. Using the atomic weights the ratio between CO2 and
carbon is:
Multiplying with the mass fraction of carbon in the
fuel we get the specific emission of CO2 (Ccarbon).
Ccarbon for a fuel with 85% carbon content will be:
for heavy fuel oil with a carbon content of 85% by
mass.
It is recommended to use direct carbon calculations.
If these data are not easily available in a first approach the
following default values can be used for the carbon content and the
factor CCarbon: µ.
Type of fuel
|
ISO Specification
|
Carbon content m/m
|
CCarbon [g CO2 /
t Fuel]
|
1 Diesel/Gasoil
|
ISO 8217 Grades DMX through
DMC
|
0.875footnote
|
3,206,000
|
2 Light Fuel Oil (LFO)
|
ISO 8217 Grades RMA through
RMD
|
0.86footnote
|
3,151,040
|
3 Heavy Fuel Oil (HFO)
|
ISO 8217 Grades RME through
RMK
|
0.85footnote
|
3,114,400
|
4 Liquid Petrol Gas (LPG)
|
|
0.81footnote
|
2,967,840
|
5 Natural Gas
|
|
0.80footnote
|
2,931,200
|