AMMONIUM NITRATE BASED FERTILIZER UN 2067

 Ammonium nitrate-based fertilizers classified as UN 2067 are uniform mixtures containing ammonium nitrate as the main ingredient within the following composition limits:

• .1 not less than 90% ammonium nitrate with not more than 0.2% total combustible/organic material calculated as carbon and with added matter, if any, which is inorganic and inert towards ammonium nitrate; or

• .2 less than 90% but more than 70% ammonium nitrate with other inorganic materials or more than 80% but less than 90% ammonium nitrate mixed with calcium carbonate and/or dolomite and/or mineral calcium sulphate and not more than 0.4% total combustible/organic material calculated as carbon; or

• .3 ammonium nitrate-based fertilizers containing mixtures of ammonium nitrate and ammonium sulphate with more than 45% but less than 70% ammonium nitrate and not more than 0.4% total combustible organic material calculated as carbon such that the sum of the percentage compositions of ammonium nitrate and ammonium sulphate exceeds 70%.

Description

Crystals, granules or prills. Wholly or partly soluble in water. Hygroscopic.

Notes:

1. All nitrate ions for which there is present in the mixture a molecular equivalent of ammonium ions should be calculated as ammonium nitrate.

2. The transport of ammonium nitrate materials which are liable to self-heating sufficient to initiate decomposition is prohibited.

3. This entry may only be used for substances that do not exhibit properties of class 1 when tested in accordance with Test Series 1 and 2 of the UN Manual of Tests and Criteria.

Characteristics

Hazard

Supports combustion. A major fire aboard a ship carrying these substances may involve a risk of explosion in the event of contamination (e.g. by fuel oil) or strong confinement. An adjacent detonation may involve a risk of explosion.

If heated strongly decomposes, risk of toxic fumes and gases which support combustion, in the cargo space and on deck.

Fertilizer dust might be irritating to skin and mucous membranes.

This cargo is hygroscopic and will cake if wet.

Stowage and segregation

"Separated by a complete compartment or hold from" combustible materials (particularly liquid), bromates, chlorates, chlorites, hypochlorites, nitrites, perchlorates, permanganates, powdered metals and vegetable fibres (e.g. cotton, jute, sisal, etc.).

"Separated from" all other goods.

"Separated from" sources of heat or ignition (see also Loading).

Not to be stowed immediately adjacent to any tank, double bottom or pipe containing heated fuel oil unless there are means to monitor and control the temperature so that it does not exceed 50°C.

If the bulkhead between the cargo space and the engine-room is not insulated to class A-60 standard, this cargo shall be stowed "away from" the bulkhead.

Hold cleanliness

Clean and dry as relevant to the hazards of the cargo.

Weather precautions

This cargo shall be kept as dry as practicable. This cargo shall not be handled during precipitation. During handling of this cargo, all non-working hatches of the cargo spaces into which this cargo is loaded, or to be loaded, shall be closed.

Loading

Trim in accordance with the relevant provisions required under sections 4 and 5 of this Code.

Prior to loading, the following provisions shall be complied with:

• .1 This cargo shall not be accepted for loading when the temperature of the cargo is above 40°C.

• .2 Prior to loading, the shipper shall provide the master with a certificate signed by the shipper stating that all the relevant conditions of the cargo required by this Code, including this individual schedule, have been met.

• .3 The fuel tanks situated under the cargo spaces to be used for the transport of this cargo shall be pressure tested to ensure that there is no leakage of manholes and piping systems leading to the tanks.

• .4 All electrical equipment, other than those of approved intrinsically safe type, in the cargo spaces to be used for this cargo shall be electrically disconnected from the power source, by appropriate means other than a fuse, at a point external to the space. This situation shall be maintained while the cargo is on board.

• .5 Due consideration shall be given to the possible need to open hatches in case of fire to provide maximum ventilation and to apply water in an emergency and the consequent risk to the stability of the ship through fluidization of the cargo.

During loading, the following provisions shall be complied with:

• .6 Bunkering of fuel oil shall not be allowed. Pumping of fuel oil in spaces adjacent to the cargo spaces for this cargo, other than the engine-room, shall not be allowed.

• .7 As far as reasonably practicable, combustible securing and protecting materials shall not be used. When wooden dunnage is necessary, only a minimum shall be used.

Precautions

This cargo shall only be accepted for loading when the competent authority is satisfied with regard to the resistance to detonation of this material based on the test.^footnote The master and officers are to note that the ship's fixed gas fire-extinguishing installation will be ineffective on fires involving this cargo and that applying copious amounts of water may be necessary. Prior to loading, the shipper shall provide the master with a certificate stating that the resistance to detonation of this material is in compliance with this requirement. Pressure on the fire mains shall be maintained for fire-fighting and fire hoses shall be laid out or be in position and ready for immediate use during loading and discharging of this cargo. No welding, burning, cutting or other operations involving the use of fire, open flame, spark- or arc-producing equipment shall be carried out in the vicinity of the cargo spaces containing this cargo except in an emergency. Smoking shall not be allowed on deck and in the cargo spaces and "NO SMOKING" signs shall be displayed on deck whenever this cargo is on board. Precautions shall be taken to avoid the penetration of this cargo into other cargo spaces, bilges and other enclosed spaces. The hatches of the cargo spaces, whenever this material is on board, shall be kept free to be capable of being opened in case of an emergency.

Appropriate precautions shall be taken to protect machinery and accommodation spaces from the dust of the cargo. Bilge wells of the cargo spaces shall be protected from ingress of the cargo. Due consideration shall be given to protect equipment from the dust of the cargo. Persons who may be exposed to the dust of the cargo shall wear goggles or other equivalent dust eye-protection and dust filter masks. Those persons shall wear protective clothing, as necessary.

Ventilation

The cargo spaces carrying this cargo shall not be ventilated during voyage.

Carriage

Hatches of the cargo spaces carrying this cargo shall be weathertight to prevent the ingress of water. The temperature of this cargo shall be monitored and recorded daily during the voyage to detect decomposition which may result in heating and oxygen depletion.

Discharge

Bunkering of fuel oil shall not be allowed. Pumping of fuel oil in spaces adjacent to the cargo spaces for this cargo, other than the engine-room, shall not be allowed. Ammonium nitrate based fertilizers are hygroscopic and may cake in overhangs, impairing safety during discharge. If this cargo has hardened, it shall be trimmed to avoid the formation of overhangs, as necessary.

Clean-up

After discharge of this cargo, the bilge wells and the scuppers of the cargo spaces shall be checked and any blockage in the bilge wells and the scuppers shall be removed.

Emergency procedures