Crude oil is a complex chemical material which is not stable
over time when stocked. Crude oils can also vary in composition over
time. In addition the use of crude oil has proven to create practical
and HSE barriers for the involved testing institutes. To overcome
this, a model immersion liquid is used to simulate crude oil. The
formulation of this crude oil model system is given below:
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.1 start with distillate Marine Fuel, DMA Gradefootnote density at 15șC: maximum 890 kg/m3,
viscosity of maximum 6 mm2/s at 40șC;
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.2 add naphthenic acid up to an acid numberfootnote of 2.5 ± 0.1 mg KOH/g;
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.3 add benzene/ toluene (1:1 ratio) up to a total
of 8.0 ± 0.2% w/w of the DMA;
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.4 add artificial seawaterfootnote up to a total of 5.0 ± 0.2% w/w
to the mixture;
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.5 add H2S dissolved in a liquid carrier
(in order to get 5 ± 1 ppm w/w H2S in the total
test liquid);
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.6 thoroughly mix the above constituents immediately
prior to use; and
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.7 once the mixture is completed, it should be
tested to confirm the mixture is compliant with the test mixture concentrations.
Note
To prevent the risk of H2S release into
the test facility, it is recommended to use a stock solution for steps
1 to 4, then fill the test containers and complete the test solution
with steps 5 and 6.