IRON OXIDE, SPENT or IRON SPONGE, SPENT UN 1376 obtained from coal gas purification
Clasification Society 2024 - Version 9.40
Statutory Documents - IMO Publications and Documents - International Codes - IMSBC Code – International Maritime Solid Bulk Cargoes Code – Resolution MSC.268(85) - Appendix 1 – Individual Schedules of Solid Bulk Cargoes - IRON OXIDE, SPENT or IRON SPONGE, SPENT UN 1376 obtained from coal gas purification

IRON OXIDE, SPENT or IRON SPONGE, SPENT UN 1376 obtained from coal gas purification

Description

Powdery material, black, brown, red or yellow. Strong odour may taint other cargo.

Characteristics

Physical properties
Size Angle of repose Bulk density (kg/m3) Stowage factor (m3/t)
Up to 20 mm Not applicable 2,222 0.45
Hazard classification
Class Subsidiary hazard(s) MHB Group
4.2 Not applicable   B

Hazard

Liable to heat and ignite spontaneously, especially if contaminated with oil or moisture. Toxic gases: hydrogen sulphide, sulphur dioxide and hydrogen cyanide may be produced. Dust may cause an explosion hazard. Liable to reduce the oxygen in the cargo space.

Stowage and segregation

"Separated from" foodstuffs.

Hold cleanliness

Clean and dry as relevant to the hazards of the cargo.

Weather precautions

This cargo shall be kept as dry as practicable. This cargo shall not be handled during precipitation. During handling of this cargo, all non-working hatches of the cargo spaces into which this cargo is loaded, or to be loaded, shall be closed.

Loading

Trim in accordance with the relevant provisions required under sections 4 and 5 of this Code.

As the density of the cargo is extremely high, the tank top may be overstressed unless the cargo is evenly spread across the tank top to equalize the weight distribution. Due consideration shall be given to ensure that the tank top is not overstressed during the voyage and during loading by a pile of the cargo.

Precautions

Prior to loading, the shipper or the manufacturer shall provide the master with a certificate stating that the cargo has been cooled and then weathered for not less than 8 weeks prior to shipment.

Ventilation

Surface ventilation only, either natural or mechanical, shall be conducted, as necessary, during the voyage for this cargo.

Carriage

For quantitative measurements of oxygen and hydrogen cyanide, suitable detectors for each gas or combination of gases shall be on board while this cargo is carried. The detectors shall be suitable for use in an atmosphere without oxygen and of certified safe type for use in explosive atmosphere. The concentrations of these gases in the cargo spaces carrying this cargo shall be measured regularly, during the voyage, and the results of the measurements shall be recorded and kept on board.

Discharge

No special requirements.

Clean-up

No special requirements.

Emergency procedures

Special emergency equipment to be carried
Protective clothing (gloves, boots, coveralls and headgear).

Self-contained breathing apparatus.

Spray nozzles.

Emergency procedures
Wear protective clothing and self-contained breathing apparatus.
Emergency action in the event of fire
Batten down; use ship's fixed fire-fighting installation, if available.

Exclusion of air may be sufficient to control fire.

Medical first aid
Refer to the Medical First Aid Guide (MFAG), as amended.

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