Chapter 3.1 – General
3.1.2 Proper Shipping Names
3.1.2 Delete Note 2 and renumber Note
3 as Note 2.
3.1.2.8 Generic or "not otherwise specified" (N.O.S.)
entries
3.1.2.8.1 In the first sentence after "special
provision 274" insert "or 318".
3.1.2.8.1.1 In the first sentence after "recognized
chemical", insert "or biological name,".
3.1.3 Mixtures and solutions containing
one dangerous substance
3.1.3 The existing section "3.1.3" and the title
are replaced with the following:
-
“3.1.3
Mixtures or solutions
NOTE: Where a substance is specifically listed
by name in the Dangerous Goods List, it shall be identified in transport
by the proper shipping name in the Dangerous Goods List. Such substances
may contain technical impurities (for example those deriving from
the production process) or additives for stability or other purposes
that do not affect its classification. However, a substance listed
by name containing technical impurities or additives for stability
or other purposes affecting its classification shall be considered
a mixture or solution (see 2.0.2.2 and 2.0.2.5).
-
3.1.3.1 A mixture or solution is not
subject to the provisions of this Code if the characteristics, properties,
form or physical state of the mixture or solution are such that it
does not meet the criteria, including human experience criteria, for
inclusion in any class.
-
3.1.3.2 A mixture or solution composed
of a single predominant substance identified by name in the Dangerous
Goods List and one or more substances not subject to the provisions
of this Code and/or traces of one or more substances identified by
name in the Dangerous Goods List, shall be assigned the UN number
and proper shipping name of the predominant substance named in the
Dangerous Goods List unless:
-
.1 The mixture or solution is identified by name
in the Dangerous Goods List;
-
.2 The name and description of the substance named
in the Dangerous Goods List specifically indicate that they apply
only to the pure substance;
-
.3 The hazard class or division, subsidiary risk(s),
packing group, or physical state of the mixture or solution is different
from that of the substance named in the Dangerous Goods List; or
-
.4 The hazard characteristics and properties of
the mixture or solution necessitate emergency response measures that
are different from those required for the substance identified by
name in the Dangerous Goods List.
-
3.1.3.3 Qualifying words such as "MIXTURE" or
"SOLUTION", as appropriate, shall be added as part of the proper shipping
name, for example, "ACETONE SOLUTION". In addition, the concentration
of the mixture or solution may also be indicated after the basic description
of the mixture or solution, for example, "ACETONE 75% SOLUTION".
-
3.1.3.4 A mixture or solution meeting the classification
criteria of this Code that is not identified by name in the Dangerous
Goods List and that is composed of two or more dangerous goods shall
be assigned to an entry that has the proper shipping name, description,
hazard class or division, subsidiary risk(s) and packing group that
most precisely describe the mixture or solution.".
3.1.4 Segregation groups
3.1.4.4 The segregation groups are amended as
follows:
|
8
|
Hypochlorites
|
| Add the following entries:
|
| UN 3485 Calcium hypochlorite,
dry, corrosive or calcium hypochlorite mixture, dry, corrosive with
more than 39% available chlorine (8.8% available oxygen)
|
| UN 3486 Calcium hypochlorite
mixture, dry, corrosive with more than 10% but not more than 39% available
chlorine
|
| UN 3487 Calcium hypochlorite,
hydrated, corrosive or calcium hypochlorite, hydrated mixture, corrosive,
with not less than 5.5% but not more than 16% water
|
|
18
|
Alkalis
|
| Add the following entry:
|
| UN 3484 Hydrazine aqueous
solution, flammable, with more than 37% hydrazine, by mass
|
|
Chapter 3.2 –
Dangerous Goods List
|
| For UN Nos. 0323, 0366,
0441, 0445, 0455, 0456, 0460 and 0500, add "347" in column (6).
|
| For UN Nos. 1002 and
1956, delete "292" in column (6).
|
| For UN
Nos. 1092, 1098, 1135, 1143, 1163, 1182, 1185, 1238, 1239, 1244, 1251,
1510, 1541, 1580, 1595, 1605, 1647, 1670, 1695, 1752, 1809, 1810,
1834, 1838, 1892, 1994, 2232, 2334, 2337, 2382, 2407, 2474, 2477,
2480, 2481, 2482, 2483, 2484, 2485, 2486, 2487, 2488, 2521, 2605,
2606, 2644, 2646, 2668, 3023, 3079 and 3246 add "354" in column (6).
|
| For UN
Nos. 1092, 1098, 1135, 1143, 1163, 1182, 1185, 1238, 1239, 1244, 1251,
1541, 1580, 1595, 1605, 1647, 1670, 1695, 1752, 1809, 1810, 1838,
1892, 1994, 2232, 2334, 2337, 2382, 2407, 2474, 2477, 2480, 2482,
2484, 2485, 2486, 2487, 2488, 2521, 2606, 2644, 2646, 2668, 3023,
3246 and 3381 to 3390 amend the code in column (7b) to read "E0".
|
| For UN Nos. 1135, 1143,
1695, 1752, 1809, 1810, 2232, 2337, 2382, 2474, 2477, 2482, 2483,
2484, 2485, 2486, 2487, 2488, 2521, 2605, 2606, 2644, 2646, 3023,
3079 and 3246 replace "P001" with "P602" in column (8).
|
| For UN Nos. 1135, 1182,
1541, 1605, 1670, 1810, 1838, 1892, 2232, 2382, 2474, 2477, 2481,
2482, 2483, 2484, 2485, 2486, 2487, 2488, 2521, 2605, 2606, 2644,
2668, 3079 and 3246 amend the code in column (13) to read "T20".
|
| For UN Nos. 1135, 1182,
1251, 1541, 1580, 1605, 1670, 1810, 1838, 1892, 2232, 2382, 2474,
2477, 2481, 2482, 2483, 2484, 2485, 2486, 2487, 2488, 2521, 2605,
2606, 2644, 2668, 3079 and 3246 add "TP37" in column (14).
|
| For UN Nos. 1194, 1222,
1261, 1865, 3094 (PG I) and 3301 (PG I), replace "P099" with "P001"
in column (8).
|
| For UN Nos. 1251 and
1580 replace "T14" with "T22" in column (13).
|
| For UN Nos. 1378, 1450,
1461, 1462, 1482 (PG II and III), 1549, 1556 (PG I, II and III), 1557
(PG I, II and III), 1564 (PG II and III), 1566 (PG II and III), 1583
(PG I, II and III), 1655 (PG I, II and III), 1707, 1935 (PG I, II
and III), 2024 (PG I, II and III), 2025 (PG I, II and III), 2026 (PG
I, II and III), 2291, 2570 (PG I, II and III), 2627, 2630, 2742, 2856,
2881 (PG I, II and III), 3141, 3144 (PG I, II and III), 3210 (PG II
and III), 3212, 3213 (PG II and III), 3214, 3219 (PG II and III),
3256, 3257, 3258, 3283 (PG I, II and III), 3284 (PG I, II and III),
3285 (PG I, II and III), 3361, 3362 and 3440 (PG I, II and III) add
"274" in column (6).
|
| For UN Nos. 1391, 1649
and 2030 (PG I), delete "329" in column (6).
|
| For UN Nos. 1450 and
3213(PG II and III), add "350" and delete "900" in column (6).
|
| For UN Nos. 1461 and
3210 (PG II and III), add "351" and delete "900" in column (6).
|
| For UN
Nos. 1482 (PG II and III) and 3214, add "353" and delete "900" in
column (6).
|
| For UN Nos. 1748 (PG
II), 2208 and 2880 (PG II and III), delete "313" in column (6).
|
| For UN Nos. 1810, 1834
and 1838, replace "8" with "6.1" in column (3) and add "8" in column
(4).
|
| For UN Nos. 1810, 1838,
2474, 2486 and 2668, replace "II" with "I" in column (5).
|
| For UN Nos. 1810, 1834,
2474 and 2668 add "TP13" in column (14).
|
| For UN Nos. 1950 and
2037, add "344" in column (6).
|
| For UN 1040
|
Add "342" in column (6).
|
| For UN 1072
|
Add "355" in column (6).
|
| For UN 1131 in column
(16) delete "see also SP 953".
|
| For UN Nos. 1259, 2845,
3194, 3392, 3394 in column (16) replace "Prohibited on any ship carrying
goods of class 1 with exceptions as in 7.2.7.1.3.2" with "Separated
longitudinally by an intervening complete compartment or hold from
Class 1".
|
| For UN 1266 (PG II and III)
|
Add "163" in column (6).
|
| For UN 1267 (PG I, II and III)
|
Add "357" in column (6).
|
| For UN 1267 (PG I)
Delete "Boiling range: 14°C upwards"in column (17).
|
| For UN 1268 (PG I)
Delete "Boiling range: 14°C upwards"in column (17).
|
| For UN 1462 Add "352"
and delete "900" in column (6).
|
| For UN 1510 Replace
"5.1" with "6.1" in column (3) and replace "6.1" with "5.1" in column
(4).
|
| For UN 1580 Replace
"P602" with "P601" in column (8).
|
| For UN 1838 Replace
"P001" with "P602" in column (8) and delete "IBC02" in column (10).
|
| For UN 1845 Delete
"III" in column (5).
|
| For UN 1977 Add "345
346" in column (6).
|
| For UN 1999 (PG II
and III) In column (2), amend the name and description to read "TARS,
LIQUID, including road oils, and cutback bitumens". Amend the alphabetical
index accordingly.
|
| For UN Nos. 2078, 2206,
2236, 2250, 2281, 2285, 2290, 2328, 2478, 2480, 2482, 2484, 2485,
2487, 2488, 3080 and 3428, insert in column (17) "Irritating to skin,
eyes and mucous membranes.".
|
| For UN 2315 Delete
"908" in column (6).
|
| For UN Nos. 2474, 2486
and 2668 amend the value in column (7a) to read "0".
|
| For UN Nos. 2481, 2483,
2486, 2605 and 3079, replace "3" with "6.1" in column (3) and replace
"6.1" with "3" in column (4).
|
| For UN Nos. 2910, 2916,
2917, 2919 and 3323, add "325" in column (6).
|
| For UN 2481
|
Replace "P601" with "P602" in
column (8).
|
| For UN 2668
|
Replace "P001 IBC99" with "P602"
in column (8) and delete "IBC99" in column (10).
|
| For UN Nos.
3077 and 3082, delete "179" and "909" in column (6).
|
| For UN Nos.
3095 (PG I), 3096 (PG I) and 3124 (PG I), replace "P099" with "P002"
in column (8).
|
| For UN 3151
|
Delete "908" in column (6).
|
| For UN 3212
|
Add "349" in column (6).
|
| For UN Nos.
3328, 3329, 3330 and 3331, add "326" in column (6).
|
| For UN Nos.
3391 to 3394, 3395 to 3399 (PG I, II and III) and 3400 (PG II and
III), add "TP36" in column (14).
|
| For UN 3468
|
Add "356" in column (6) and replace
"P099" with "P205" in column (8).
|
| For UN 3474
|
In column (2), amend the name
and description to read "1-HYDROXYBENZOTRIAZOLE MONOHYDRATE" and in
column (6), delete "28". Amend the alphabetical index accordingly.
|
| For UN Nos. 3480 and
3481,
|
add "348" in
column (6).
|
| For UN 3126
(PGII), 3127 (PGII), 3128 (PGII), 3131 (PGII) and 3132 (PGII) insert
"T3" in column (13) and "TP33" in column (14).
|
| For UN 3126
(PGIII), 3127 (PGIII), 3128 (PGIII), 3131 (PGIII) and 3132 (PGIII)
insert "T1" in column (13) and "TP33" in column (14).
|
| For UN 0020,
0021, 0243, 0244, 0245, 0246, 0248, 0249, 0250, 0301, 0303, 0322,
0354, 0355, 0356, 0357, 0358, 0359, 0380 insert in column (17) ","
after "under deck" in the last sentence.
|
| For UN 0501
replace "S-X" with "S-Y" in column (15).
|
| For UN 0216,
Amend column (2) to read "TRINITRO-m-CRESOL". Amend the alphabetical
index accordingly.
|
| For UN 1110,
Amend column (2) to read "n-AMYL METHYL KETONE". Amend the alphabetical
index accordingly.
|
| For UN 1125,
Amend column (2) to read "n-BUTYLAMINE". Amend the alphabetical index
accordingly.
|
| For UN 1128,
Amend column (2) to read "n-BUTYL FORMATE". Amend the alphabetical
index accordingly.
|
| For UN 1131,
Delete "953" in column (6) and replace in column (16) "Prohibited
on any ship carrying goods of class 1 with exceptions as in 7.2.7.1.3.2"
with "Separated longitudinally by an intervening complete compartment
or hold from Class 1".
|
| For UN 1143,
Replace "Category B" with "Category D" in column (16).
|
| For UN 1274,
Amend column (2) to read "n-PROPANOL (PROPYL ALCOHOL, NORMAL)". Amend
the alphabetical index accordingly.
|
| For UN 1276,
Amend column (2) to read "n-PROPYL ACETATE". Amend the alphabetical
index accordingly.
|
| For
UN 1348, Amend column (2) to read "SODIUM DINITRO-o-CRESOLATE, WETTED
with not less than 15% water, by mass". Amend the alphabetical index
accordingly.
|
| For UN 1391,
Replace "e.g., metallic sodium, suspended in a flammable liquid such
as toluene, xylene, naphta, kerosene, etc" with "suspended in a liquid"
in column (17).
|
| For UN 1471
(PG II) amend column (2) to read "LITHIUM HYPOCHLORITE, DRY or LITHIUM
HYPOCHLORITE MIXTURE" and amend the alphabetical index accordingly.
|
| For
UN 1486, 1498 and 1499, add "964" in column (6).
|
| For UN 1510,
Replace in column (17) "Toxic if swallowed, by skin contact or by
vapour inhalation" with "Highly toxic if swallowed, by skin contact
or by inhalation".
|
| For UN 1512,
Delete "B2" in column (11).
|
| For UN 1579,
Amend column (2) to read "4-CHLORO-o-TOLUIDINE HYDROCHLORIDE, SOLID".
Amend the alphabetical index accordingly.
|
| For UN 1591,
Amend column (2) to read "o-DICHLOROBENZENE". Amend the alphabetical
index accordingly.
|
| For UN 1598,
Amend column (2) to read "DINITRO-o-CRESOL". Amend the alphabetical
index accordingly.
|
| For UN 1647,
Replace "Category C" with "Category D" in column (16).
|
| For UN 1649,
Delete "*" in column (15) and delete "May have a flashpoint within
the range of flammable liquids." and "*If flammable : F-E, S-D" in
column (17).
|
| For UN 1661,
Amend column (2) to read "NITROANILINES (o-, m-, p-)". Amend the alphabetical
index accordingly.
|
| For UN 1663,
Amend column (2) to read "NITROPHENOLS (o-, m-, p-)". Amend the alphabetical
index accordingly.
|
| For UN 1673,
Amend column (2) to read "PHENYLENEDIAMINES (o-, m-, p-)". Amend the
alphabetical index accordingly.
|
| For UN 1810,
Replace "Category C" with "Category D" in column (16) and add in column
(17) "Highly toxic if swallowed, by skin contact or by inhalation.".
|
| For UN 1834,
Replace "Category C" with "Category D" in column (16) and add in column
(17) "Highly toxic if swallowed, by skin contact or by inhalation.".
|
| For UN 1838,
Replace "Category C" with "Category D" in column (16) and replace
in column (17) "Vapour irritates mucous membranes" with "Highly toxic
if swallowed, by skin contact or by inhalation. Causes burns to skin,
eyes and mucous membranes.".
|
| For UN 1865,
Amend column (2) to read "n-PROPYL NITRATE". Amend the alphabetical
index accordingly.
|
| For UN 1913,
Replace "Category B" with "Category D" in column (16).
|
| For UN 1951,
Replace "Category B" with "Category D" in column (16).
|
| For UN 1963,
Replace "Category B" with "Category D" in column (16).
|
| For UN 1970,
Replace "Category B" with "Category D" in column (16).
|
| For UN 1977,
Delete in column (17) in the second sentence "of the gas".
|
| For UN 2030,
Delete "*" in column (15) and delete "*If flammable : F-E, S-C (S-C
is a special case)" in column (17).
|
| For UN 2187,
Replace "Category B" with "Category D" in column (16).
|
| For UN 2201,
Replace "Category B" with "Category D" in column (16).
|
| For UN 2227,
Amend column (2) to read "n-BUTYL METHACRYLATE, STABILIZED". Amend
the alphabetical index accordingly.
|
| For UN 2247,
Amend column (2) to read "n-DECANE". Amend the alphabetical index
accordingly.
|
| For UN 2278,
Amend column (2) to read "n-HEPTENE". Amend the alphabetical index
accordingly.
|
| For UN 2337,
Replace "Category B" with "Category D" in column (16).
|
| For UN 2364,
Amend column (2) to read "n-PROPYLBENZENE". Amend the alphabetical
index accordingly.
|
| For UN 2384,
Amend column (2) to read "DI-n-PROPYL ETHER". Amend the alphabetical
index accordingly.
|
| For UN 2398,
Amend column (2) to read "METHYL tert-BUTYL ETHER". Amend the alphabetical
index accordingly.
|
| For UN 2455,
Delete "F-C, S-V" in column (15).
|
| For UN 2474,
Replace "Category B" with "Category D" in column (16) and replace
in column (17) "Toxic if swallowed, by skin contact or by inhalation"
with "Highly toxic if swallowed, by skin contact or by inhalation".
|
| For UN 2477,
Add "Clear of living quarters." in column (16).
|
| For UN 2481,
Replace in column (17) "Toxic by inhalation" with "Highly toxic if
swallowed, by skin contact or by inhalation".
|
| For UN 2482,
Amend column (2) to read "n-PROPYL ISOCYANATE". Amend the alphabetical
index accordingly.
|
| For UN 2483,
Replace in column (17) "Toxic if swallowed, by skin contact or by
inhalation" with "Highly toxic if swallowed, by skin contact or by
inhalation".
|
| For UN 2485,
Amend column (2) to read "n-BUTYL ISOCYANATE". Amend the alphabetical
index accordingly.
|
| For UN 2486,
Replace in column (17) "Toxic by inhalation" with "Highly toxic if
swallowed, by skin contact or by inhalation".
|
| For UN 2591,
Replace "Category B" with "Category D" in column (16).
|
| For UN 2605,
Replace in column (17) "Toxic if swallowed, by skin contact or by
inhalation" with "Highly toxic if swallowed, by skin contact or by
inhalation".
|
| For UN 2606,
Replace "Category E" with "Category D" in column (16).
|
| For UN 2644,
Replace "Category C" with "Category D" in column (16).
|
| For UN 2668,
Replace "Category A" with "Category D" in column (16) and replace
in column (17) "Toxic if swallowed, by skin contact or by inhalation"
with "Highly toxic if swallowed, by skin contact or by inhalation".
|
| For UN 2671,
Amend column (2) to read "AMINOPYRIDINES (o-, m-, p-)". Amend the
alphabetical index accordingly.
|
| For UN 2740,
Amend column (2) to read "n-PROPYL CHLOROFORMATE". Amend the alphabetical
index accordingly.
|
| For UN 2743,
Amend column (2) to read "n-BUTYL CHLOROFORMATE". Amend the alphabetical
index accordingly.
|
| For UN 2949,
Insert "," after "HYDROSULPHIDE" in column (2).
|
| For UN 3056,
Amend column (2) to read "n-HEPTALDEHYDE". Amend the alphabetical
index accordingly.
|
| For UN 3065
(PG II and III), Insert "," after "BEVERAGES" in column (2).
|
| For UN 3079,
Replace in column (17) "Toxic if swallowed, by skin contact or by
inhalation" with "Highly toxic if swallowed, by skin contact or by
inhalation".
|
| For UN Nos
3101, 3102, 3103, 3104, 3105, 3106, 3107, 3108, 3109, 3110, 3111,
3112, 3113, 3114, 3115, 3116, 3117, 3118, 3119 and 3120, Add at the
end of current text in column (17) "May evolve irritant or toxic fumes.".
|
| For UN 3124,
Replace in column (17) "Toxic if swallowed, by skin contact or by
inhalation" with "Highly toxic if swallowed, by skin contact or by
inhalation".
|
| For UN 3166:
|
| Amend column
(2) to read "ENGINE, INTERNAL COMBUSTION or VEHICLE, FLAMMABLE GAS
POWERED or VEHICLE, FLAMMABLE LIQUID POWERED or ENGINE, FUEL CELL,
FLAMMABLE GAS POWERED or ENGINE, FUEL CELL, FLAMMABLE LIQUID POWERED
or VEHICLE, FUEL CELL, FLAMMABLE GAS POWERED or VEHICLE, FUEL CELL,
FLAMMABLE LIQUID POWERED".
|
| Amend column
(6) to read "312 356 961 962".
|
| Amend column
(15) to read "*".
|
| Amend column
(16) to read "Category A".
|
| Amend column
(17) to read "Type of articles transported under this entry include
internal combustion engines, compression/ignition engines, fuel cell
powered engines, motor vehicles, hybrid vehicles, motorcycles and
boats. *F-D, S-U for gases or F-E, S-E for liquids.".
|
| Amend the alphabetical
index accordingly.
|
| For UN 3171:
|
| Amend column
(6) to read "240 961 962".
|
| Amend column
(15) to read "F-I, S-I".
|
| Amend column
(16) to read "Category A".
|
| Amend column
(17) to read "Type of articles transported under this entry include
vehicles or equipment powered by wet batteries, sodium batteries or
lithium batteries with the batteries installed, such as electrically-powered
cars, lawnmowers, wheelchairs and other mobility aids.".
|
| For UN 3359
In column (2), amend the proper shipping name to read "FUMIGATED CARGO
TRANSPORT UNIT". Delete "910" in column (6). In column (17), amend
"FUMIGATED UNIT" to read "FUMIGATED CARGO TRANSPORT UNIT", delete
"Fumigants shall not be applied to the contents of a cargo transport
unit once it has been loaded aboard the ship. A closed cargo transport
unit that has been fumigated is not subject to the provisions of this
Code if it has been completely ventilated either by opening the doors
of the unit or by mechanical ventilation after fumigation and if the
date of ventilation is marked on the fumigation warning sign (see
also special provision 910)" and add "See also 5.5.2.". Amend the
proper shipping name in the index accordingly.
|
| For
UN Nos. 3381, 3382, 3383, 3385, 3387 and 3389 Replace in column (17)
"Highly toxic by inhalation. Toxic if swallowed or by skin contact."
with "Highly toxic if swallowed, by skin contact or by inhalation."
and "significant" with "highly".
|
| For UN Nos.
3384, 3386, 3388 and 3390 Replace in column (17) "Toxic by inhalation,
if swallowed or by skin contact." with "Highly toxic if swallowed,
by skin contact or by inhalation." and "significant" with "highly".
|
Add the following new entries:
|
(1)
|
(2)
|
(3)
|
(4)
|
(5)
|
(6)
|
(7a)
|
(7b)
|
(8)
|
(9)
|
(10)
|
(11)
|
(13)
|
(14)
|
(15)
|
(16)
|
(17)
|
| 0509
|
POWDER, SMOKELESS
|
1.4C
|
–
|
–
|
–
|
0
|
E0
|
P114(b)
|
PP48
|
–
|
–
|
–
|
–
|
F-B, S-Y
|
Category 09
|
Substances based on nitrocellulose
used as a propellant.
|
| 1471
|
LITHIUM
HYPOCHLORITE,
DRY or LITHIUM
HYPOCHLORITE
MIXTURE
|
5.1
|
–
|
III
|
223
|
5 kg
|
E1
|
P002
LP02
|
–
|
IBC08
|
B3
|
T1
|
TP33
|
F-H, S-Q
|
Category
A.
Ventilation may be required. The possible need to open
hatches in case of fire to provide maximum ventilation and to apply water
in an emergency, and the consequent risk to the stability of the ship
through flooding of the cargo spaces, shall be considered before loading.
"Separated from" ammonium compounds, acids, cyanides, hydrogen peroxide
and liquid organic substances. "Away from" sources of heat.
|
See entry above.
|
| 3482
|
ALKALI METAL DISPERSION,
FLAMMABLE or ALKALINE
EARTH METAL
DISPERSION,
FLAMMABLE
|
4.3
|
3
|
I
|
182
183
|
0
|
E0
|
P402
|
PP31
|
–
|
–
|
–
|
–
|
F-G, S-N
|
Category
D.
”Separated from” acids
|
Finely divided alkali or alkaline
earth metal suspended in a flammable liquid. Reacts violently with
moisture, water or acids, evolving hydrogen, which may be ignited by the
heat of the reaction.
|
| 3483
|
MOTOR FUEL ANTI-KNOCK
MIXTURE, FLAMMABLE
|
6.1
|
3
P
|
I
|
–
|
0
|
E5
|
P602
|
–
|
–
|
–
|
T14
|
TP2
TP13
|
F-E, S-D
|
Category D.
Clear
of living quarters.
Shaded from radiant heat.
|
Volatile flammable liquids evolving
toxic vapour. Mixture of tetraethyllead or tetramethyllead with ethylene
dibromide and ethylene dichloride. Insoluble in water. Highly toxic if
swallowed, by skin contact or by inhalation.
|
| 3484
|
HYDRAZINE AQUEOUS
SOLUTION, FLAMMABLE with
more than 37%
hydrazine, by
mass
|
8
|
3
6.1
|
I
|
–
|
0
|
E0
|
P001
|
–
|
–
|
–
|
T10
|
TP2
TP13
|
F-E, 
|
Category D.
Clear
of living quarters. Segregation as for class 3, but "away from" class
4.1. "Separated from" acids.
|
Colourless flammable liquid.
Powerful reducing agent, burns readily. Toxic if swallowed, by skin
contact or by inhalation. Causes burns to skin, eyes and mucous
membranes. Reacts violently with acids.
|
| 3485
|
CALCIUM HYPOCHLORITE,
DRY, CORROSIVE or
CALCIUM HYPOCHLORITE
MIXTURE, DRY, CORROSIVE
with more than
39% available
chlorine (8.8% available
oxygen)
|
5.1
|
8
|
II
|
314
|
1 kg
|
E2
|
P002
|
PP85
|
–
|
–
|
–
|
–
|
F-H, S-Q
|
Category D.
Cargo
transport units shall be shaded from direct sunlight and stowed away from
sources of heat. Packages in cargo transport units shall be stowed so as
to allow for adequate air circulation throughout the cargo. "Separated
from" ammonium compounds, acids, cyanides, hydrogen peroxides and liquid
organic substances.
|
White or yellowish corrosive solid
(powder, granules or tablets) with chlorine-like odour. Soluble in water.
May cause fire in contact with organic material or
ammonium compounds. Substances are liable to exothermic decomposition at
elevated temperatures.
This condition may lead to fire or
explosion. Decomposition can be initiated by heat or by impurities (e.g.,
powdered metals (iron, manganese, cobalt, magnesium) and their
compounds). Liable to heat slowly.
Reacts with acids,
evolving chlorine, an irritating, corrosive and toxic gas. In the
presence of moisture, corrosive to most metals.
Causes
burns to skin, eyes and mucous membranes.
|
| 3486
|
CALCIUM HYPOCHLORITE
MIXTURE, DRY, CORROSIVE
with more than
10% but not
more than 39% available
chlorine
|
5.1
|
8
|
III
|
314
|
5 kg
|
E1
|
P002
|
PP85
|
–
|
–
|
–
|
–
|
F-H, S-Q
|
Category D.
Cargo
transport units shall be shaded from direct sunlight and stowed away from
sources of heat. Packages in cargo transport units shall be stowed so as
to allow for adequate air circulation throughout the cargo.
"Separated from" ammonium compounds, acids, cyanides,
hydrogen peroxides and liquid organic substances.
|
White or yellowish corrosive solid
(powder, granules or tablets) with chlorine-like odour. Soluble in water.
May cause fire in contact with organic material or
ammonium compounds. Substances are liable to exothermic decomposition at
elevated temperatures.
This condition may lead to fire or
explosion. Decomposition can be initiated by heat or by impurities (e.g.,
powdered metals (iron, manganese, cobalt, magnesium) and their
compounds). Liable to heat slowly.
Reacts with acids,
evolving chlorine, an irritating, corrosive and toxic gas. In the
presence of moisture, corrosive to most metals. Causes burns to skin,
eyes and mucous membranes.
|
| 3487
|
CALCIUM HYPOCHLORITE,
HYDRATED, CORROSIVE or
CALCIUM
HYPOCHLORITE,
HYDRATED MIXTURE,
CORROSIVE
with not less
than 5.5% but not more than
16% water
|
5.1
|
8
|
II
|
314
322
|
1 kg
|
E2
|
P002
|
PP85
|
–
|
–
|
–
|
–
|
F-H, S-Q
|
Category D.
Cargo
transport units shall be shaded from direct sunlight and stowed away from
sources of heat. Packages in cargo transport units shall be stowed so as
to allow for adequate air circulation throughout the cargo.
"Separated from" ammonium compounds, acids, cyanides,
hydrogen peroxides and liquid organic substances.
|
White or yellowish corrosive solid
(powder, granules or tablets) with chlorine-like odour. Soluble in water.
May cause fire in contact with organic material or
ammonium compounds. Substances are liable to exothermic decomposition at
elevated temperatures. This condition may lead to fire or explosion.
Decomposition can be initiated by heat or by impurities (e.g., powdered
metals (iron, manganese, cobalt, magnesium) and their compounds).
Liable to heat slowly.
Reacts with acids,
evolving chlorine, an irritating, corrosive and toxic gas. In the
presence of moisture, corrosive to most metals. Causes burns to skin,
eyes and mucous membranes.
|
| 3487
|
CALCIUM HYPOCHLORITE,
HYDRATED, CORROSIVE or
CALCIUM
HYPOCHLORITE,
HYDRATED MIXTURE,
CORROSIVE
with not less
than 5.5% but not more than
16% water
|
5.1
|
8
|
III
|
223
314
|
5 kg
|
E1
|
P002
|
PP85
|
–
|
–
|
–
|
–
|
F-H, S-Q
|
Category D.
Cargo
transport units shall be shaded from direct sunlight and stowed away from
sources of heat. Packages in cargo transport units shall be stowed so as
to allow for adequate air circulation throughout the cargo.
"Separated from" ammonium compounds, acids, cyanides,
hydrogen peroxides and liquid organic substances.
|
See entry above.
|
| 3488
|
TOXIC BY INHALATION LIQUID,
FLAMMABLE, CORROSIVE,
N.O.S. with an
inhalation toxicity
lower than or equal to 200
ml/m3
and saturated vapour
concentration
greater than
or equal to 500 LC50
|
6.1
|
3
8
|
I
|
274
|
0
|
E0
|
P601
|
–
|
–
|
–
|
T22
|
TP2
TP13
|
F-E, S-D
|
Category D.
Clear
of living quarters.
Segregation as for class 3 but "away
from" class 4.1.
|
A variety of toxic liquids which
present a highly toxic inhalation hazard as well as being flammable and
corrosive. Highly toxic if swallowed, by skin contact or by inhalation.
Causes burns to skin, eyes and mucous membranes.
|
| 3489
|
TOXIC BY INHALATION LIQUID,
FLAMMABLE, CORROSIVE,
N.O.S. with an
inhalation toxicity
lower than or equal to 1000
ml/m3
and saturated vapour
concentration
greater than
or equal to 10 LC50
|
6.1
|
3
8
|
I
|
274
|
0
|
E0
|
P602
|
–
|
–
|
–
|
T20
|
TP2
TP13
|
F-E, S-D
|
Category D. Clear of living
quarters. Segregation as for class 3 but "away from" class 4.1.
|
A variety of toxic liquids which
present a highly toxic inhalation hazard as well as being flammable and
corrosive. Highly toxic if swallowed, by skin contact or by inhalation.
Causes burns to skin, eyes and mucous membranes.
|
| 3490
|
TOXIC BY INHALATION LIQUID,
WATER-REACTIVE,
FLAMMABLE, N.O.S. with an
inhalation toxicity lower than or
equal
to 200 ml/m3 and saturated
vapour
concentration greater than
or equal to 500
LC50
|
6.1
|
4.3
3
|
I
|
274
|
0
|
E0
|
P601
|
–
|
–
|
–
|
T22
|
TP2
TP13
|
F-G, S-N
|
Category D. Clear of living
quarters. Segregation as for class 3 but "away from" classes 3 and
8.
|
A variety of toxic liquids which
present a highly toxic inhalation hazard as well as being water reactive
and flammable. Highly toxic if swallowed, by skin contact or by
inhalation.
|
| 3491
|
TOXIC BY INHALATION LIQUID,
WATER-REACTIVE,
FLAMMABLE, N.O.S. with an
inhalation toxicity lower than or
equal
to 1000 ml/m3 and
saturated vapour
concentration
greater than or equal to 10 LC50
|
6.1
|
4.3
3
|
I
|
274
|
0
|
E0
|
P602
|
–
|
–
|
–
|
T20
|
TP2
TP13
|
F-G, S-N
|
Category D. Clear of living
quarters. Segregation as for class 3 but "away from" classes 3 and
8.
|
A variety of toxic liquids which
present a highly toxic inhalation hazard as well as being waterreactive
and flammable. Highly toxic if swallowed, by skin contact or by
inhalation.
|
| 3492
|
TOXIC BY INHALATION
LIQUID, CORROSIVE,
FLAMMABLE, N.O.S. with
an
inhalation toxicity lower than
or
equal to 200 ml/m3 and
saturated vapour
concentration
greater than or equal to 500
LC50
|
6.1
|
8
3
|
I
|
274
|
0
|
E0
|
P601
|
–
|
–
|
–
|
T22
|
TP2
TP13
|
F-E, S-D
|
Category D. Clear of living
quarters. Segregation as for class 3 but "away from" class 4.1.
|
A variety of toxic liquids which
present a highly toxic inhalation hazard as well as being flammable and
corrosive. Highly toxic if swallowed, by skin contact or by inhalation.
Causes burns to skin, eyes and mucous membranes.
|
| 3493
|
TOXIC BY INHALATION
LIQUID, CORROSIVE,
FLAMMABLE, N.O.S. with
an
inhalation toxicity lower than
or
equal to 1000 ml/m3 and
saturated vapour
concentration
greater than or equal to 10 LC50
|
6.1
|
8
3
|
I
|
274
|
0
|
E0
|
P602
|
–
|
–
|
–
|
T20
|
TP2
TP13
|
F-E, S-D
|
Category D. Clear of living
quarters. Segregation as for class 3 but "away from" class 4.1.
|
A variety of toxic liquids which
present a highly toxic inhalation hazard as well as being flammable and
corrosive. Highly toxic if swallowed, by skin contact or by inhalation.
Causes burns to skin, eyes and mucous membranes.
|
| 3494
|
PETROLEUM SOUR CRUDE
OIL, FLAMMABLE, TOXIC
|
3
|
6.1
|
I
|
343
|
0
|
E0
|
P001
|
–
|
–
|
–
|
T14
|
TP2
TP13
|
F-E, S-E
|
Category D. Clear of living
quarters.
|
Immiscible with water. Evolves
hydrogen sulphide, which is a flammable, toxic gas with a foul odour,
heavier than air (1.2). Toxic if swallowed, by skin contact or by
inhalation
|
| 3494
|
PETROLEUM SOUR CRUDE
OIL, FLAMMABLE, TOXIC
|
3
|
6.1
|
II
|
343
|
1 l
|
E2
|
P001
|
–
|
IBC02
|
–
|
T7
|
TP2
|
F-E, S-E
|
Category D. Clear of living
quarters.
|
See entry above.
|
| 3494
|
PETROLEUM SOUR CRUDE
OIL, FLAMMABLE, TOXIC
|
3
|
6.1
|
III
|
343
|
5 l
|
E1
|
P001
|
–
|
IBC03
|
–
|
T4
|
TP1
|
F-E, S-E
|
Category C. Clear of living
quarters.
|
See entry above.
|
| 3495
|
IODINE
|
8
|
6.1
|
III
|
279
|
5 kg
|
E1
|
P002
|
–
|
IBC08
|
B3
|
T1
|
TP33
|
F-A, S-B
|
Category B. Clear of living
quarters. "Separated from" ammonia.
|
Bluish-black solid with a metallic
lustre and a pungent odour. Melting point: 114°C. Below its melting
point, may evolve vapours which are irritating to skin, eyes and mucous
membranes. Slightly soluble in water but soluble in most organic
solvents. Corrosive to most metals.
|
| 3496
|
BATTERIES,
NICKEL-METAL
HYDRIDE
|
9
|
–
|
–
|
117
963
|
0
|
E0
|
See
SP963
|
–
|
–
|
–
|
–
|
–
|
F-A,
S-I
|
Category A. "Away
from" sources of heat.
|
Nickel-metal hydride
button cells or nickel-metal hydride cells or batteries packed with or
contained in equipment are not subject to the provisions of this
Code.
|
and amend the alphabetical index and Appendix
A accordingly.
|