Any of a group of compounds having the characteristic formula
R (N3)x. R may be almost any metal atom, a hydrogen
atom, a halogen atom, the ammonium radical, certain inorganic complexes
and organic radical. The azide group has a chain structure N=N=N.
Electrons involved in such kinds of bonds have complicated orbits,
and are extremely sensitive to additional input of external energy,
which makes them capable of breaking the existing bonds. The breaking
of the bonds affects the whole molecule which undergoes spontaneous
decomposition. All the heavy metal azides, hydrogen azide and most
the light metal azides are explosives. Many of the organic azides
are explosives