This schedule shall not apply to consignments of materials which are
accompanied by a declaration submitted prior to loading by the shipper and stating that
they have no self-heating properties when transported in bulk.
Description
Metal drillings usually wet or contaminated with such materials as
unsaturated cutting oil, oily rags and other combustible material.
Characteristics
Physical properties
|
Size
|
Angle of
repose
|
Bulk density
(kg/m3)
|
Stowage factor
(m3/t)
|
Not
applicable
|
Not
applicable
|
Various
|
Various
|
Hazard classification
|
Class
|
Subsidiary
hazard(s)
|
MHB
|
Group
|
4.2
|
Not
applicable
|
|
B
|
Hazard
These materials are liable to self-heat and ignite spontaneously,
particularly when in a finely divided form, wet or contaminated with such materials as
unsaturated cutting oil, oily rags and other combustible matter.
Excessive amounts of cast iron borings or organic materials may encourage
heating. Self-heating or inadequate ventilation may cause dangerous depletion of oxygen
in cargo spaces.
Stowage and segregation
"Separated from" foodstuffs.
Hold cleanliness
Clean and dry as relevant to the hazards of the cargo.
Weather precautions
This cargo shall be kept as dry as practicable. This cargo shall not be
handled during precipitation. During handling of this cargo, all non-working hatches of
the cargo spaces into which this cargo is loaded, or to be loaded, shall be closed.
Loading
During loading, the material shall be compacted in the cargo space as
frequently as practicable with a bulldozer or other means. The bilge of each cargo space
in which the cargo is loaded shall be kept as dry as practicable. After loading, the
cargo shall be trimmed to eliminate peaks and compacted. Wooden wet battens and dunnage
shall be removed from the cargo space before the cargo is loaded.
Precautions
The temperature of this cargo shall be measured prior to and during
loading. The temperature of the cargo in the stockyard shall be measured at points
between 200 mm and 350 mm from the surface of the cargo pile. This cargo shall only be
accepted for loading when the temperature of the cargo prior to loading does not exceed
55°C. If the temperature of the cargo in any cargo space exceeds 90°C during loading,
loading shall be suspended and shall not be recommenced until the temperature of the
cargo in all cargo spaces has fallen below 85°C. The ship shall not depart unless the
temperature of the cargo in all cargo spaces is below 65°C and has shown a steady or
downward trend in temperature for at least eight hours.
Ventilation
The cargo spaces carrying this cargo shall not be ventilated during
voyage.
Carriage
The surface temperature of the cargo shall be monitored and recorded daily
during the voyage. Temperature readings shall be taken in such a way as not to require
entry into the cargo space or, alternatively, if entry is required for this purpose, at
least two sets of self-contained breathing apparatus, additional to those required by
SOLAS regulation II-2/10.10 shall be provided.
Discharge
Entry into the cargo spaces containing this cargo shall only be permitted
for trained personnel wearing self-contained breathing apparatus when the main hatches
are open and after adequate ventilation is conducted or for personnel using appropriate
breathing apparatus.footnote
Clean-up
Prior to washing out the residues of this cargo, any oil spillages shall be
cleaned from the tank tops and the bilge wells of the cargo spaces for this cargo.
Emergency procedures
Special emergency equipment to
be carried
|
Self-contained breathing
apparatus
|
Emergency
procedures
|
Nil
|
Emergency action in the event
of fire
|
Whilst at sea, any rise in
surface temperature of the material indicates a self-heating reaction
problem. If the temperature should rise to 80°C, a potential fire situation
is developing and the ship should make for the nearest suitable port. Batten
down.
Water should not be used at sea.
Early
application of an inert gas to a smouldering situation may be
effective.
|
Medical first aid
|
Refer to the Medical First Aid
Guide (MFAG), as amended.
|
Remarks
In port, copious quantities of water may be used, but due consideration
should be given to factors affecting the stability of the ship.