17.20.1 Cargoes that may be carried individually
under the requirements of this Code, notably butane, butylenes and
butadiene, may be carried as mixtures subject to the provisions of
this section. These cargoes may variously be referred to as "Crude
C4", "Crude butadiene", "Crude steam-cracked C4", "Spent steam-cracked
C4", "C4 stream", "C4 raffinate", or may be shipped under a different
description. In all cases, the material safety data sheets (MSDS)
shall be consulted as the butadiene content of the mixture is of prime
concern as it is potentially toxic and reactive. While it is recognized
that butadiene has a relatively low vapour pressure, if such mixtures
contain butadiene they shall be regarded as toxic and the appropriate
precautions applied.
17.20.2 If the mixed C4 cargo shipped under the
terms of this section contains more than 50% (mole) of butadiene,
the inhibitor precautions in 17.8 shall apply.
17.20.3 Unless specific data on liquid expansion
coefficients is given for the specific mixture loaded, the filling
limit restrictions of chapter 15 shall be calculated as if the cargo
contained 100% concentration of the component with the highest expansion
ratio.