4.19
Materials
Goal
To ensure that the cargo containment system, primary and secondary barriers, the
thermal insulation, adjacent ship structure and other materials in the cargo
containment system are constructed from materials of suitable properties for the
conditions they will experience, both in normal service and in the event of
failure of the primary barrier, where applicable.
4.19.1
Materials forming ship structure
4.19.1.1 To determine the grade of plate and sections
used in the hull structure, a temperature calculation shall be performed for all
tank types when the cargo temperature is below -10°C. The following assumptions
shall be made in this calculation:
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.1 the primary barrier of all tanks shall be
assumed to be at the cargo temperature;
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.2 in addition to .1, where a complete or
partial secondary barrier is required, it shall be assumed to be at the
cargo temperature at atmospheric pressure for any one tank only;
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.3 for worldwide service, ambient temperatures
shall be taken as 5°C for air and 0ºC for seawater. Higher values may be
accepted for ships operating in restricted areas and, conversely, lower
values may be fixed by the Administration for ships trading to areas where
lower temperatures are expected during the winter months;
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.4 still air and seawater conditions shall be
assumed, i.e. no adjustment for forced convection;
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.5 degradation of the thermal insulation
properties over the life of the ship due to factors such as thermal and
mechanical ageing, compaction, ship motions and tank vibrations, as defined
in 4.19.3.6 and 4.19.3.7, shall be assumed;
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.6 the cooling effect of the rising boil-off
vapour from the leaked cargo shall be taken into account, where
applicable;
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.7 credit for hull heating may be taken in
accordance with 4.19.1.5, provided the heating arrangements are in
compliance with 4.19.1.6;
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.8 no credit shall be given for any means of
heating, except as described in 4.19.1.5; and
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.9 for members connecting inner and outer
hulls, the mean temperature may be taken for determining the steel
grade.
The ambient temperatures used in the design, described in this paragraph,
shall be shown on the International Certificate of Fitness for the Carriage of
Liquefied Gases in Bulk required in 1.4.4.
4.19.1.2 The shell and deck plating of the ship and all
stiffeners attached thereto shall be in accordance with recognized standards. If the
calculated temperature of the material in the design condition is below -5°C due to
the influence of the cargo temperature, the material shall be in accordance with
table 6.5.
4.19.1.3 The materials of all other hull structures for
which the calculated temperature in the design condition is below 0°C, due to the
influence of cargo temperature and that do not form the secondary barrier, shall
also be in accordance with table 6.5. This includes hull structure supporting the
cargo tanks, inner bottom plating, longitudinal bulkhead plating, transverse
bulkhead plating, floors, webs, stringers and all attached stiffening members.
4.19.1.4 The hull material forming the secondary
barrier shall be in accordance with table 6.2. Where the secondary barrier is formed
by the deck or side shell plating, the material grade required by table 6.2 shall be
carried into the adjacent deck or side shell plating, where applicable, to a
suitable extent.
4.19.1.5 Means of heating structural materials may be
used to ensure that the material temperature does not fall below the minimum allowed
for the grade of material specified in table 6.5. In the calculations required in
4.19.1.1, credit for such heating may be taken in accordance with the following:
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.1 for any transverse hull structure;
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.2 for longitudinal hull structure referred to
in 4.19.1.2 and 4.19.1.3 where colder ambient temperatures are specified,
provided the material remains suitable for the ambient temperature
conditions of +5°C for air and 0°C for seawater with no credit taken in the
calculations for heating; and
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.3 as an alternative to .2, for longitudinal
bulkhead between cargo tanks, credit may be taken for heating, provided the
material remain suitable for a minimum design temperature of -30°C, or a
temperature 30°C lower than that determined by 4.19.1.1 with the heating
considered, whichever is less. In this case, the ship's longitudinal
strength shall comply with SOLAS regulation II-1/3-1 for both when those bulkhead(s) are considered
effective and not.
4.19.1.6 The means of heating referred to in 4.19.1.5
shall comply with the following requirements:
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.1 the heating system shall be arranged so
that, in the event of failure in any part of the system, standby heating can
be maintained equal to not less than 100% of the theoretical heat
requirement;
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.2 the heating system shall be considered as an
essential auxiliary. All electrical components of at least one of the
systems provided in accordance with 4.19.1.5.1 shall be supplied from the
emergency source of electrical power; and
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.3 the design and construction of the heating
system shall be included in the approval of the containment system by the
Administration or recognized organization acting on its behalf.
4.19.2
Materials of primary and secondary barriers
4.19.2.1 Metallic materials used in the construction of
primary and secondary barriers not forming the hull, shall be suitable for the
design loads that they may be subjected to, and be in accordance with, table 6.1,
6.2 or 6.3.
4.19.2.2 Materials, either non-metallic or metallic but
not covered by tables 6.1, 6.2 and 6.3, used in the primary and secondary barriers
may be approved by the Administration or recognized organization acting on its
behalf, considering the design loads that they may be subjected to, their properties
and their intended use.
4.19.2.3 Where non-metallic materials, including
composites, are used for, or incorporated in the primary or secondary barriers, they
shall be tested for the following properties, as applicable, to ensure that they are
adequate for the intended service:
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.1 compatibility with the cargoes;
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.2 ageing;
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.3 mechanical properties;
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.4 thermal expansion and contraction;
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.5 abrasion;
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.6 cohesion;
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.7 resistance to vibrations;
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.8 resistance to fire and flame spread; and
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.9 resistance to fatigue failure and crack
propagation.
4.19.2.4 The above properties, where applicable, shall
be tested for the range between the expected maximum temperature in service and +5°C
below the minimum design temperature, but not lower than -196°C.
4.19.2.5.1 Where non-metallic materials, including
composites, are used for the primary and secondary barriers, the joining processes
shall also be tested as described above.
4.19.2.5.2 Guidance on the use of non-metallic
materials in the construction of primary and secondary barriers is provided in
appendix 4.
4.19.2.6 Consideration may be given to the use of
materials in the primary and secondary barrier, which are not resistant to fire and
flame spread, provided they are protected by a suitable system such as a permanent
inert gas environment, or are provided with a fire-retardant barrier.
4.19.3
Thermal insulation and other materials used in cargo containment systems
4.19.3.1 Load-bearing thermal insulation and other
materials used in cargo containment systems shall be suitable for the design
loads.
4.19.3.2 Thermal insulation and other materials used in
cargo containment systems shall have the following properties, as applicable, to
ensure that they are adequate for the intended service:
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.1 compatibility with the cargoes;
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.2 solubility in the cargo;
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.3 absorption of the cargo;
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.4 shrinkage;
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.5 ageing;
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.6 closed cell content;
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.7 density;
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.8 mechanical properties, to the extent that
they are subjected to cargo and other loading effects, thermal expansion and
contraction;
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.9 abrasion;
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.10 cohesion;
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.11 thermal conductivity;
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.12 resistance to vibrations;
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.13 resistance to fire and flame spread;
and
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.14 resistance to fatigue failure and crack
propagation.
4.19.3.3 The above properties, where applicable, shall
be tested for the range between the expected maximum temperature in service and 5°C
below the minimum design temperature, but not lower than -196°C.
4.19.3.4 Due to location or environmental conditions,
thermal insulation materials shall have suitable properties of resistance to fire
and flame spread and shall be adequately protected against penetration of water
vapour and mechanical damage. Where the thermal insulation is located on or above
the exposed deck, and in way of tank cover penetrations, it shall have suitable fire
resistance properties in accordance with recognized standards or be covered with a
material having low flame-spread characteristics and forming an efficient approved
vapour seal.
4.19.3.5 Thermal insulation that does not meet
recognized standards for fire resistance may be used in hold spaces that are not
kept permanently inerted, provided its surfaces are covered with material with low
flame-spread characteristics and that forms an efficient approved vapour seal.
4.19.3.6 Testing for thermal conductivity of thermal
insulation shall be carried out on suitably aged samples.
4.19.3.7 Where powder or granulated thermal insulation
is used, measures shall be taken to reduce compaction in service and to maintain the
required thermal conductivity and also prevent any undue increase of pressure on the
cargo containment system.
4.20
Construction processes
Goal
To define suitable construction processes and test procedures in order to ensure,
as far as reasonably practical, that the cargo containment system will perform
satisfactorily in service in accordance with the assumptions made at the design
stage.
4.20.1.1 All welded joints of the shells of independent
tanks shall be of the in-plane butt weld full penetration type. For dome-to-shell
connections only, tee welds of the full penetration type may be used depending on
the results of the tests carried out at the approval of the welding procedure.
Except for small penetrations on domes, nozzle welds shall also be designed with
full penetration.
4.20.1.2 Welding joint details for type C independent
tanks, and for the liquid-tight primary barriers of type B independent tanks
primarily constructed of curved surfaces, shall be as follows:
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.1 all longitudinal and circumferential joints
shall be of butt welded, full penetration, double vee or single vee type.
Full penetration butt welds shall be obtained by double welding or by the
use of backing rings. If used, backing rings shall be removed except from
very small process pressure vessels. Other edge preparations may be
permitted, depending on the results of the tests carried out at the approval
of the welding procedure; and
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.2 the bevel preparation of the joints between
the tank body and domes and between domes and relevant fittings shall be
designed according to a standard acceptable to the Administration or
recognized organization acting on its behalf. All welds connecting nozzles,
domes or other penetrations of the vessel and all welds connecting flanges
to the vessel or nozzles shall be full penetration welds.
4.20.1.3 Where applicable, all the construction
processes and testing, except that specified in 4.20.3, shall be done in accordance
with the applicable provisions of chapter 6.
4.20.2
Design for gluing and other joining processes
The design of the joint to be glued (or joined by some other process
except welding) shall take account of the strength characteristics of the joining
process.
4.20.3
Testing
4.20.3.1 All cargo tanks and process pressure vessels
shall be subjected to hydrostatic or hydropneumatic pressure testing in accordance
with 4.21 to 4.26, as applicable for the tank type.
4.20.3.2 All tanks shall be subject to a tightness test
which may be performed in combination with the pressure test referred to in
4.20.3.1.
4.20.3.3 Requirements with respect to inspection of
secondary barriers shall be decided by the Administration or recognized organization
acting on its behalf in each case, taking into account the accessibility of the
barrier (see 4.6.2).
4.20.3.4 The Administration may require that for ships
fitted with novel type B independent tanks, or tanks designed according to 4.27 at
least one prototype tank and its supporting structures shall be instrumented with
strain gauges or other suitable equipment to confirm stress levels. Similar
instrumentation may be required for type C independent tanks, depending on their
configuration and on the arrangement of their supports and attachments.
4.20.3.5 The overall performance of the cargo
containment system shall be verified for compliance with the design parameters
during the first full loading and discharging of the cargo, in accordance with the
survey procedure and requirements in 1.4 and the requirements of the Administration
or recognized organization acting on its behalf. Records of the performance of the
components and equipment essential to verify the design parameters, shall be
maintained and be available to the Administration.
4.20.3.6 Heating arrangements, if fitted in accordance
with 4.19.1.5 and 4.19.1.6, shall be tested for required heat output and heat
distribution.
4.20.3.7 The cargo containment system shall be
inspected for cold spots during, or immediately following, the first loaded voyage.
Inspection of the integrity of thermal insulation surfaces that cannot be visually
checked shall be carried out in accordance with recognized standards.