This schedule shall only apply to seed cakes and other residues of processed
oily vegetables which are substantially free from flammable solvents or other flammable
chemicals, meet the criterion for self-heating solids specified in 9.2.3.3 and do not
meet any of the criteria for dangerous goods specified in 9.2.2.
Description
Residues remaining after oil has been mechanically expelled or extracted by
solvent or other chemical processes from oil-bearing seeds, grains, cereals, fruit or
vegetables. This cargo may be shipped in the form of pulp, meals, cake, pellets and
expellers.
Characteristics
Physical properties
|
Size
|
Angle of
repose
|
Bulk density
(kg/m3)
|
Stowage factor
(m3/t)
|
Various
|
Variousfootnote
|
478 to
719
|
1.39 to
2.09
|
Hazard classification
|
Class
|
Subsidiary
hazard(s)
|
MHB
|
Group
|
Not
applicable
|
Not
applicable
|
SH
|
B
|
Hazard
This cargo may heat spontaneously. Liable to oxidize, causing subsequent
reduction of oxygen in the cargo space. Carbon dioxide may also be produced.
Loading of dry pellets using cargo blowers may present a risk of dust explosion.
Stowage and segregation
Unless otherwise determined by the competent authority, segregation as
required for class 4.2 materials.
Hold cleanliness
Clean and dry as relevant to the hazards of the cargo.
Weather precautions
This cargo shall be kept as dry as practicable. This cargo shall not be
handled during precipitation. During handling of this cargo, all non-working hatches of
the cargo spaces into which this cargo is loaded, or to be loaded, shall be closed.
Loading
Trim in accordance with the relevant provisions required under sections 4
and 5 of this Code. Solvent-extracted cargo shall only be accepted for loading when the
cargo is substantially free from flammable solvent. Before shipment, solvent-extracted
cargoes shall be properly aged; the duration of ageing required varies with the oil
content.
This cargo shall only be accepted for loading when the temperature of the
cargo is not higher than the ambient temperature plus 10°C, or 55°C, whichever is lower.
All sources of ignition shall be considered and avoided to prevent possible dust
explosions. Blower equipment shall be earthed. Piping shall be electrically continuous
or earthed.
Precautions
Entry of personnel into cargo spaces for this cargo shall not be permitted
until tests have been carried out and it has been established that the oxygen content
has been restored to a normal level.footnote
Persons who may be exposed to the dust of the cargo shall wear a dust filter masks,
protective eyewear and protective clothing, as necessary.
The temperature of this cargo shall be measured regularly at a number of depths in the
cargo spaces and recorded during the voyage. If the temperature of the cargo reaches
55°C and continues to increase, ventilation for the cargo shall be stopped.
If self-heating continues, then carbon dioxide or inert gas shall be introduced into the
cargo space. Notwithstanding the previous requirement, in the case of solvent-extracted
cargoes, the use of carbon dioxide or inert gas shall be withheld until fire is
apparent.
Electrical circuits for equipment in cargo spaces which are unsuitable for use in an
explosive atmosphere shall be isolated by removal of links in the system other than
fuses.
Spark-arresting screens shall be fitted to ventilators to the cargo spaces containing
this cargo.
Ventilation
Surface ventilation either natural or mechanical shall be conducted, as
necessary, for removing any residual solvent vapour. To prevent self-heating of the
cargo, caution is required when using mechanical ventilation.
Carriage
Hatches of the cargo spaces carrying this cargo shall be weathertight to
prevent the ingress of water.
Discharge
No special requirements.
Clean-up
No special requirements.
Emergency procedures
Special emergency equipment to
be carried
|
Self-contained breathing
apparatus.
|
Emergency
procedures
|
Wear self-contained breathing
apparatus.
|
Emergency action in the event
of fire
|
Batten down; use ship's fixed
CO2 fire-fighting installation, if fitted.
|
Medical first aid
|
Refer to the Medical First Aid
Guide (MFAG), as amended.
|
Remarks
The use of CO2 or inert gas is limited to controlling the fire,
and further amounts may need to be injected from time to time during passage to reduce
the oxygen content in the hold. On arrival in port, the cargo will need to be removed in
stages to reach the seat of the fire.